Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Question
Chapter 7, Problem 7.9P
Interpretation Introduction
(a)
Interpretation:
Whether
Concept introduction:
Nucleophile is an atom or group containing negative charge or lone pair of electrons.
Interpretation Introduction
(b)
Interpretation:
Whether
Concept introduction:
Nucleophile is an atom or group containing negative charge or lone pair of electrons.
Interpretation Introduction
(c)
Interpretation:
Whether
Concept introduction:
Nucleophile is an atom or group containing negative charge or lone pair of electrons.
Interpretation Introduction
(d)
Interpretation:
Whether
Concept introduction:
Nucleophile is an atom or group containing negative charge or lone pair of electrons.
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(e) Compare the solubility in water of the following compounds. Explain.
CH.CH,COOH
HOOCCH;COOH
(d) Write the chemical equation for the reaction of propanoic acid, CH;CH;COOH
with each the following reagents.
Magnesium metal
(ii) Aqueous potassium hydroxide
Draw the structure of each of the following molecules. (a) pentanoic anhydride; (b) hexanoic propanoic anhydride;
(c) ethanoic 3-methylpentanoic anhydride
What is/are the product(s) of the following acid/base reaction?
OH
(A)
NaOCH3
Hint: Draw resonance structures!!
(B)
OCH3
(C)
O
(D)
Chapter 7 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 7 - Prob. 7.1PCh. 7 - Prob. 7.2PCh. 7 - Prob. 7.3PCh. 7 - Prob. 7.4PCh. 7 - Prob. 7.5PCh. 7 - Prob. 7.6PCh. 7 - Prob. 7.7PCh. 7 - Prob. 7.8PCh. 7 - Prob. 7.9PCh. 7 - Prob. 7.10P
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Prob. 7.13PCh. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Prob. 7.16PCh. 7 - Prob. 7.17PCh. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - Prob. 7.22PCh. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Prob. 7.31PCh. 7 - Prob. 7.32PCh. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Prob. 7.42PCh. 7 - Prob. 7.43PCh. 7 - Prob. 7.44PCh. 7 - Prob. 7.45PCh. 7 - Prob. 7.46PCh. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - Prob. 7.50PCh. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.1YTCh. 7 - Prob. 7.2YTCh. 7 - Prob. 7.3YTCh. 7 - Prob. 7.4YTCh. 7 - Prob. 7.5YTCh. 7 - Prob. 7.6YTCh. 7 - Prob. 7.7YTCh. 7 - Prob. 7.8YTCh. 7 - Prob. 7.9YTCh. 7 - Prob. 7.10YTCh. 7 - Prob. 7.11YTCh. 7 - Prob. 7.12YTCh. 7 - Prob. 7.13YTCh. 7 - Prob. 7.14YTCh. 7 - Prob. 7.15YT
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- (b) Addition of HBr to the alkene in the presence of peroxide form radical intermediates. Based on the following reaction, use the curved arrows to HBr B (preferred product) ROOR (i) show the initiation step of this reaction. (ii) draw the possible structures of the two radicals formed in the propagation step. (ii) explain the formation of the preferred product B.arrow_forwardDraw the structure of each of the following molecules. (a) cyclohexyl butanoate; (b) 1,1-dimethylethyl hexanoate; (c) phenyl 4,4-dinitroheptanoatearrow_forwardDraw the structures of the following compounds. (a) isobutyl bromidearrow_forward
- from each. a) b) c) Predict the product of the following reactions. Provide the major organic product Br Br Br →→ Li CN acetone Na₂Sarrow_forward2) which are of the following are ions aromatic Species? DO AQarrow_forward(b) Draw the structural formula for each of the following compounds. (i) 2,2,3-trimethylpentan-3-ol(ii) 2-methyl-3-phenylbut-2-enal(iii) 5-chloro-2-methylheptan-3-olarrow_forward
- Draw structures of the following derivatives. ) the (E) isomer of the ethyl imine of propiophenonearrow_forwardIn the following acid - base reactions, a) Draw Lewis structures of the reactants and the products. b) Determine which species are acting as electrophiles (acids) and which are acting as nucleophiles (bases). c) Use the curved - arrow formalism to show the movement of electron pairs in these reactions and the imaginary movement in the resonance hybrids of the products. d) Indicate which reactions are best termed Brønsted-Lowry acid - base reactions i. CH3CHO + HCI-- > CH3CH2O + + Cl- ii. CH3CHO + OH- - - > CH3CO-(OH) Harrow_forwardDraw the structures for each of the following molecules. (a) 2-fluorotoluene; (b) 4-ethoxytoluene; (c) 2-ethoxyanisole;(d) 1,3-diphenylheptane; (e) 4,4-diphenyl-1-octene; (f) benzylbenzenearrow_forward
- 6. (Chapter 15-Q37) Indole is an aromatic heterocyclic that has a benzene ring fused to a pyrrole ring. Answer the following questions. Indole 6(a) What is the hybridization of N in this molecule? = 6(b) How many pi electrons N contributes to the ring? = 6() Which orbitals contribute to form a sigma bond between N and H in this molecule? = 6(c) What is the electronic relationship of Indole to naphthalene? Give the answer by comparing number of rings and number of pi electrons in both compounds, write x rings, y pi electrons=|arrow_forwardQ4 (a) Calculate the pOH pf following solutions: (i) 0.01M solution of KOH considering 100% dissociation. (ii) 0.1M solution of NH4OH considering 5% dissociation. (b) Write IUPAC name to the following hydrocarbons and justify the answer. (i) (ii)arrow_forwardArrange the following compounds in increasing order of their property as indicated :(i) CH3COCH3, C6H5COCH3, CH3CHO(reactivity towards nucleophilic addition reaction)(ii) Cl—CH2—COOH, F—CH2—COOH, CH3—COOH (acidic character)arrow_forward
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