General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 23, Problem 23.69SP
Draw and name compounds that meet the following descriptions:
- (a) Three different amides with the formula C5H11NO
- (b) Three different esters with the formula C6H12O2
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Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C5H11NO(b) Three different esters with the formula C6H12O2
TRUE OR FALSE
(a) There are three amines with the molecular formula C3H9N.
(b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group.
(c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid.
(d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°.
(e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O.
(f) The molecular formula of the smallest carboxylic acid is C2H4O2.
Classify each compound (a)–(f) as one of the following: (i) amide, (ii) ester, or(iii) carboxylic acid. (a) CH3COOCH3 (b) RCONHR (c) C6H5COOH
Chapter 23 Solutions
General Chemistry: Atoms First
Ch. 23.1 - Prob. 23.1PCh. 23.1 - Prob. 23.2PCh. 23.1 - Prob. 23.3PCh. 23.1 - Prob. 23.4CPCh. 23.2 - Prob. 23.5PCh. 23.2 - Prob. 23.6PCh. 23.3 - Prob. 23.7PCh. 23.3 - Prob. 23.8PCh. 23.3 - Prob. 23.9CPCh. 23.4 - Prob. 23.10P
Ch. 23.4 - Prob. 23.11PCh. 23.4 - Prob. 23.12PCh. 23.4 - Prob. 23.13PCh. 23.5 - Prob. 23.14PCh. 23.5 - Draw structures corresponding to the following...Ch. 23.6 - Draw structures corresponding to the following...Ch. 23.6 - Write the products from reaction of the following...Ch. 23.6 - Reaction of Br2/FeBr3 with toluene (methylbenzene)...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Draw structures corresponding to the following...Ch. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22CPCh. 23.10 - Prob. 23.23PCh. 23.10 - Prob. 23.24PCh. 23.10 - Prob. 23.25PCh. 23.11 - Prob. 23.26PCh. 23.12 - Show the structure of glyceryl trioleate, a fat...Ch. 23.13 - Prob. 23.28PCh. 23.13 - Prob. 23.29PCh. 23.13 - Prob. 23.30PCh. 23.13 - Prob. 23.31CPCh. 23.13 - Prob. 23.32PCh. 23 - Prob. 23.33CPCh. 23 - Prob. 23.34CPCh. 23 - Prob. 23.35CPCh. 23 - Prob. 23.36CPCh. 23 - Prob. 23.37CPCh. 23 - Prob. 23.38CPCh. 23 - Prob. 23.39CPCh. 23 - Prob. 23.40SPCh. 23 - Prob. 23.41SPCh. 23 - Prob. 23.42SPCh. 23 - Prob. 23.43SPCh. 23 - Prob. 23.44SPCh. 23 - Prob. 23.45SPCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - What is wrong with each of the following...Ch. 23 - What are the IUPAC names of the following alkanes?Ch. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw structures corresponding to the following (a)...Ch. 23 - Prob. 23.65SPCh. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SPCh. 23 - Prob. 23.68SPCh. 23 - Draw and name compounds that meet the following...Ch. 23 - Prob. 23.70SPCh. 23 - Prob. 23.71SPCh. 23 - Prob. 23.72SPCh. 23 - Prob. 23.73SPCh. 23 - Prob. 23.74SPCh. 23 - Prob. 23.75SPCh. 23 - Prob. 23.76SPCh. 23 - Prob. 23.77SPCh. 23 - Prob. 23.78SPCh. 23 - Prob. 23.79SPCh. 23 - Prob. 23.80SPCh. 23 - Prob. 23.81SPCh. 23 - Prob. 23.82SPCh. 23 - Prob. 23.83SPCh. 23 - Prob. 23.84SPCh. 23 - Prob. 23.85SPCh. 23 - Prob. 23.86SPCh. 23 - Prob. 23.87SPCh. 23 - There are two isomeric fat molecules whose...Ch. 23 - Prob. 23.89SPCh. 23 - What is a nucleotide, and what three kinds of...Ch. 23 - What are the names of the sugars in DNA and RNA,...Ch. 23 - Prob. 23.92SPCh. 23 - Prob. 23.93SPCh. 23 - Prob. 23.94SPCh. 23 - Prob. 23.95SPCh. 23 - Prob. 23.96SPCh. 23 - Prob. 23.97SPCh. 23 - Prob. 23.98CHPCh. 23 - Prob. 23.99CHPCh. 23 - Prob. 23.100CHPCh. 23 - Prob. 23.101CHPCh. 23 - Write full structures for the following peptides,...Ch. 23 - Prob. 23.103CHPCh. 23 - Prob. 23.104CHPCh. 23 - Prob. 23.105CHPCh. 23 - Prob. 23.106CHPCh. 23 - Elaidic acid, a component of so-called trans fats,...Ch. 23 - Fumaric acid is an organic substance widely used...
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- (a) Compound Z is a tertiary aromatic amine with the formula, C8H11N. Provide a chemical structure for compound Z. (b)nDraw the structure of the product formed exclusively when nitrous acid reacts with Z.arrow_forwardGive the chemical tests to distinguish between the following pairs of compounds :(i) Ethyl amine and Aniline(ii) Aniline and Benzylaminearrow_forwardfive different benzenoid compounds with molecular formula C9H11NO2 which illustrate the functional groups: (i) alcohol (ii) amine (iii) ester (iv) phenol (v) amidearrow_forward
- (b) Draw the structural formula for each of the following compounds. Lukiskan formula struktur bagi setiap sebatian berikut. (i) 2-iodo-4-methylpentan-3-amine (ii) 1,1-dibromo-2-chloro-2-methylbutane (iii) 2-ethyl-6-fluorophenolarrow_forwardGive the chemical tests to distinguish between the following pairs of compounds :(i) Methylamine and Dimethylamine(ii) Aniline and N-methylanilinearrow_forward3. Draw structures for the following: (a) an acid and an ester having the formula C 2 H 4O 2 (b) 2-alkenes having the formula C 5H 10 (3 isomers) (c) 1° amines having the formula C 4 H 11 N (4 isomers)arrow_forward
- (a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.arrow_forwardIndicate whether each statement is true or false: (a) Fat molecules contain amide bonds. (b) Phosphoplipids can be zwitterions. (c) Phospholipids form bilayers in water in order to have their long hydrophobic tails interact favorably with each other, leaving their polar heads to the aqueous environment.arrow_forwardWrite down the distinguishing features among the following: (a) primary,secondary,tertiary Alcohols (b)primary, secondary, tertiary amines (c) carboxylic acid,ester and amide (d)Alkenes Alkynesarrow_forward
- Give suggestion the structural formula for the following compounds. a) m-aminobenzoic acidb) 4-benzyl-2,7-dimethyl-8-phenyloctenearrow_forwardDraw structures corresponding to these names:(a) 4-Methylpentanamide (b) N-Ethyl-N-methylpropanamidearrow_forwardThe C-N distance in an amide bond is approximately 1.32 Å. A typical C-N single bond is 1.45Å, while a typical C=N double bond is 1.25 Å. Explain this observation and describe how thebonding in amides restricts the conformations amides can adopt.arrow_forward
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