The conversion of benzoic acid to benzylamine by using reductive amination is to be shown. Concept introduction: Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 1

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 2

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 3

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 4

Question

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

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Answer 5

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 6

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 7

Chapter 19, Problem 19.47SP

(a)

Interpretation Introduction

Interpretation:

The conversion of benzoic acid to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The conversion of benzaldehyde to benzylamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The conversion of pyrrolidine to N-ethylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The conversion of cyclohexanone to N-cyclohexylpyrrolidine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The conversion of pentan 1,5-dioic acid to pentan 1,5-diamine by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine.

Reduction of amide is a process in which amide group is reduced to amines in the presence of reducing agents. Lithium aluminium hydride is a good reducing agent for such processes.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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Chapter 19 Solutions