(a) Interpretation: The mechanism of reaction between trichloromethane and sodium iodide is to be predicted. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 1

Question

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

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Give a clear handwritten answer..and give the mechanism of given bleow reaction

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(a) What reagents would be used for the conversion of alkene A into the target? (b) What reaction is involved in the conversion of alcohol B into alkene A? Suggest a reagent that might affect this transformation. (c) Give a retrosynthetic analysis showing the disconnection of B, the synthons produced that lead to the synthetic equivalents given (draw their structures).

Answer 2

Question

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

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Answer 3

Question

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

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Answer 4

Question

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

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Answer 5

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

Answer 6

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 7

Chapter 9, Problem 9.87AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of reaction between trichloromethane and sodium iodide is to be predicted.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism of reaction between benzyl chloride, cyclohexene and organolithium is to be predicted.

Concept introduction:

Alkyl lithium is an organolithium reagent. It contains a carbon-lithium bond. It is used in organic synthesis and to transfer an organic group to substrate.

A carbon atom which contains one lone pair of electron and two atoms attached to it is known as carbene. They are highly reactive species.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the mechanism of reaction between trichloromethane and sodium iodide is shown in Figure 1.

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Chapter 9 Solutions