Physics for Scientists and Engineers
Physics for Scientists and Engineers
6th Edition
ISBN: 9781429281843
Author: Tipler
Publisher: MAC HIGHER
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Chapter 38, Problem 9P
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Table 1.2 Structures and Cell Dimensions of Some Elements and Compounds Element or compound 7803838 2 2 2 2 2 5 Al Be Pt Si Ag Na Structure Agl ZnS CdS fec hcp fcc Diamond bcc hcp fcc Diamond fec bcc fec Diamond fec bcc hep LiH NaCl AgBr MnO CsCl TIBr Cu Zn (B-brass) Cesium chloride CuF Sodium chloride Sodium chloride Sodium chloride Sodium chloride Cesium chloride Cesium chloride Zincblende Zincblende Zincblende Zincblende a, Å 4.04 2.27 5.56 3.56 2.88 2.51 3.61 5.65 4.07 2.86 3.92 5.43 4.08 4.28 2.66 4.08 5.63 5.77 4.43 4.11 3.97 2.94 4.26 6.47 5.41 5.82 c, Å 3.59 4.07 4.94
4) Molybdenum has a BCC crystal structures, the density of molybdenum is 10.22 g/cm³ and its atomic mass is 95.94 g/mol. What are the atomic concentration, the lattice parameter a and the atomic radius of molybdenum. What is the atomic concentration in the primitive cell? 5) Tungsten (W) has the BCC crystal structure. The radius of the W atom is 0.1371 nm. The atomic mass of W is 183.8 amu (g/mol). Calculate the number of W atoms per unit volume and the density of W (NA = 6.02 x 10²3).
You are preparing to compete in the Physics Olympics. Your instructor is coaching you by providing you with challenging problems of the type you might see on an Olympics exam. He comes up with the following problem and gives you 15 minutes to solve it: Imagine a perfectly rigid HCl molecule that does not stretch as it rotates. The equilibrium separation of its ions is 0.127 5 nm. There are two isotopes for chlorine on the sample, Cl-35 and Cl-37. This results in double peaks in the molecular spectrum as shown. (a) Find an expression for the difference in the frequency between the peaks to the right of the gap as a function of the masses of the two chlorine isotopes and the quantum number J. (b) Estimate the difference in frequency numerically for J = 0, without consulting tables. Quick! Get to work!
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