Concept explainers
(a)
Interpretation:The reason for the following structure for not being the correct legitimate Lewis structure should be explained.
Concept introduction:A Lewis structure is a diagrammatic view of a molecule, where lone pair of electrons is represented in dots, bonds are represented with lines & formal charge of each atom is mentioned near the atom.
(b)
Interpretation: An item on the checklist of the legitimate Lewis structure has been violated by the given structure for
Concept introduction: A Lewis structure is a diagrammatic view of a molecule, where lone pair of electrons is represented in dots, bonds are represented with lines & formal charge of each atom is mentioned near the atom.
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Organic Chemistry: A Guided Inquiry
- Consider the generic polyatomic ion XY3". Element X is the least electronegative. For neutral atoms, element X has 7 valence electrons and element Y has 6. The highest occupied principal energy level of the central atom is greater than 2. A. How many total valence electrons are in the molecule. B. Draw a BEST Lewis structure (i.e. a major resonance contributor) for this molecule. Show all valence electrons on your structure. C. If you haven't already, add the formal charge of each atom to the structure. Show at least one sample calculation for formal charge. D. Outline 4 short bullet points (~several words each) that explain why your structure from part B is the best one. Hint: think about what makes a valid structure and what makes a best structure. E. Perform a calculation to determine the average bond order between the X and Y atoms in your structure from part B. No credit will be given for just a number. F. Draw one more valid resonance structure other than the one from part B.…arrow_forward4. Write the Lewis dot (electron dot) symbol for each covalent molecule. Remember the number of unpaired electrons in the Lewis dot symbol of the atom determines the number of bonds each atom makes. If your molecule has unpaired electrons you are not done. If your molecule has the wrong number of bonds for some atoms it is wrong. Try a different arrangement of atoms. Working left to right will help you. Show loan pairs. a. HCN b. CH3COOH c. H₂CCONHCH3 d. HCCH e. C6H12arrow_forward2. Consider the resonance structures below may only A C. yongary] B C D a. On each structure (A-D) show all lone pair electrons. b. Provide arrows that show electron movement from A to B, B to C, and C to D. Which is the "most contributing” resonance form (A, B, C, or D)? Explain your choice. d. Draw the resonance hybrid for this molecule (use “delta” 8+ or - to show partial charges).arrow_forward
- H. H H. H. molecule> H. atoms. Select only one type of bond in each molecule. If there are multiples of one bond type for a molecule, select them all. Do not highlightarrow_forwardConsider the molecules — BrF5. A. Draw the best Lewis structure for this molecule. Label any atoms with nonzero formal charge. B. Label each bond angle. As part of your answer be sure to include if it is more or less than the ideal bond angle. C. What is the electron geometry around the bromine atom? D. Are the bonds in the molecule polar? E. Is the overall molecule polar? — CH2 F2 . A. Draw the best Lewis structure for this molecule. B. Label each bond angle. Answers for A-D here: C. Redraw the shape of the molecule. Draw all dipoles. D. Is the overall molecule polar? — Consider the molecule CH2 CF2 . A. Draw the best Lewis structure for this molecule. B. Label each bond angle. C. Redraw the shape of the molecule (according to the exacting specifications of your instructor). Draw all dipoles. D. Is the overall molecule polar?arrow_forwarda. 1. Draw all resonance structures for the following molecules. Mention which ones are major and minor resonance structures. Do not forget to show the flow of electrons to go from one resonance to another. C. CH₂ of b. In OH OCH3 OCH 3arrow_forward
- ents V Soul (TV series) O REPRESENTATIONS OF ORGANIC MOLECULES Drawing a skeletal structure from a Lewis structure Convert the Lewis structure below into a skeletal structure. Н—С— Н H. H- H- Н—С—Н H. HH H. H- Н—С—С—С—С—С—С—С- Н C=C H- H. H. H. Н—С— Н H. ct+ Click and drag to start drawing a structure. HIC CIH HICarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non- zero formal charges. c* :0: н н || .C. Click and drag to start drawing a H H structure.arrow_forward3a.Draw the best Lewis structure for the HClO3 acid molecule. (Hint: the acidic H is bonded to O in an oxy-acid molecule).Evaluate each atom using formal charge to prove you have the best structure. Show your math work as well as your formal charge answers. 3b. Draw all the resonance structures for the ClO3– polyatomic anion. (Hint: make sure you have the best initial structure first!)arrow_forward
- 17. a For the following species, draw two valid resonance structure(s). HINT: Draw in lone pairs. H Resonance Structure 1 Resonance Structure 2 b. Draw in arrows on the structures above to show how you got from the original resonance structure to your structure. c. Compare the resonance structures and rank all three structures (circle the appropriate structure). Explain why on the line provided #1(Original, RS 1, RS 2), #2(Original, RS 1, RS 2), # 3 (Original, RS 1, RS 2), 18. What type of bonds hold organic molecules together? How are they different than the bonds that hold inorganic molecules together? Be specific, I want more than just names of bonds. 19. For the following molecule draw in all the dipole moments using 8+ and 8-. :O: H 20. BONUS Why can an sp³ hybridized carbon not form a double bond?arrow_forwardDetermine if the structural formula below is an acceptable Lewis structures for organic compounds. Point out the problems in cases where structure is invalid. :0: CH3 CH-C-Ö-CH–CH3 A. This is not the correct Lewis structure. B. No, All atoms do not have a zero formal charge, therefore this is not the correct Lewis structure. C. All atoms have a zero formal charge, therefore this is the correct Lewis structure. D. Oxygen has a formal charge of 1+.arrow_forwardRank from most to least reactive in a SNAR reaction? Type letters in order from most to least reactive, no spaces or punctuation Br Br NO₂ A Br B NO₂ O₂N. NO₂ с NO₂ Br NO₂ D NO₂arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning