(a)
To determine: The product that is formed when given diene reacts with methyl acetylenecarboxylate, a strong dienophile.
Interpretation: The product that is formed when given diene reacts with methyl acetylenecarboxylate, a strong dienophile is to be stated.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and the diene adds to the one side of the dienophile. Thus, they have syn stereochemistry. In Diels-Alder reaction, the diene behaves like an electron rich species, whereas the dienophile behaves like an electron poor species.
(b)
To determine: The path by which the strongly exothermic decarboxylation takes place.
Interpretation: The path by which the strongly exothermic decarboxylation takes place is to be stated.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and the diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
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Organic Chemistry (9th Edition)
- 10. The following compound was produced in a Diels-Alder reaction. COOH a) How many sp³ hybridized carbons are in this molecule? b) Is this molecule chiral? c) Are the carboxylic acid substituents electron donating group or electron withdrawing group? d) Draw the diene and dienophile which would react together to give this product.arrow_forwardThe diene shown below will NOT react in a Diels-Alder reaction. Why not? Select one: A. The compound is not a conjugated diene. B. The compound is lacking in electron withdrawing groups. O C. This compound cannot adopt the s-cis conformation. D. The compound is lacking in electron donating groups.arrow_forwardRank the following dienes in their rate of reaction with the same dienophile in a Diels-Alder reaction. For example, 1 = fastest or most reactive diene, 4 = slowest or least reactive diene.arrow_forward
- The diene shown below will NOT react in a Diels-Alder reaction. Why not? Select one: DA. The compound is not a conjugated diene. OB. This compound cannot adopt the s-cis conformation. C. The compound is lacking in electron donating groups. ⒸD. The compound is lacking in electron withdrawing groups.arrow_forwardDraw the structures of the diene and dienophile that yield the following enantiomeric products in the Diels-Alder reaction below: Diene: Dienophile: Do the products represent an endo or an exo addition of dienophile to diene? left product is endo, right product is exo left product is exo, right product is endo both products are endo both products are exoarrow_forwardTrue or False: Acetylene is a naturally occurring conjugated diene True or False: The Diels-Alder reaction has the stereochemistry of the dienophile is retained in the product. True or False: When looking at kinetic vs. thermodynamic products the kinetic product predominates at low temperature. True or False: the mechanism of the Diels-Alder reaction is three π bonds break; one σ bond and two π bonds form.arrow_forward
- 6.) For the following reactions, please draw the structures of both the diene and dienophile that would afford the depicted Diels Alder adducts. 1. Cl ? ? cl Diene Dienophile cl Cl 2. CH3 O CH3 ? CH3 Diene Dienophile CH3 3. ? + ? Diene Dienophile 4. CH3 ? + Diene Dienophile CH3arrow_forwardFor the Diels-Alder reaction, identify the diene, the dienophile, and the Diels-Alder adduct. H3CO. R OCH3 LOCH3 R H3CO R compound A compound B compound C Compound A is a: Compound B is a: Compound C is a:arrow_forwardDraw the structures of the diene and dienophile that would be used in the diels alder reaction to synthesize the following compounds. Label each structure as diene or dienophile.arrow_forward
- Draw the diene and dienophile that are needed to prepare the following Diels-Alder product. Diene: draw structure. Dienophile: draw structure ..arrow_forward2. Please rank the following dienophiles in their rate of reaction with the same diene in a Diels-Alder reaction (i.e. 1= fastest or most reactive dienophile, 4 = slowest or least reactive dienophile). Put your answer on the line below each structure. 3. Please rank the following dienes in their rate of reaction with the same dienophile in a Diels-Alder reaction (i.e. 1= fastest or most reactive diene, 4 = slowest or least reactive diene). Put your answer on the line below each structure. OMe OMe OMe |arrow_forwardWrite a general rule that can be used to predict the major product of a Diels–Alder reaction between an alkene with an electron-withdrawing substituent and a diene with a substituent that can donate electrons by resonance depending on the location of the substituent on the diene.arrow_forward