Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 11, Problem 11.32QE
(a)
Interpretation Introduction
Interpretation:
The compound (
(b)
Interpretation Introduction
Interpretation:
The relative magnitudes of three other properties of
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A 5.4-L closed vessel is filled with 0.46 g of liquid ethanol. This ethanol containing closed vessel
is placed in the freezer and reaches the vapor pressure of 6.65 torr at -11 C.
(i) Is there any liquid ethanol remained in the closed vessel when the container is removed
and warmed to the temperature of 25 C? Justify your answer.
(ii) How many grams of liquid ethanol remained in the vessel at 2.0 C?
The enthalpy changes of vaporization, AH,vap of ethanol is 40.5 kJ/mol.
The molar mass of ethanol is 46.07 g/mol.
Methyl salicylate, C₈H₈O₃, the odorous constituent of oil of wintergreen, has a vapor pressure of 1.00 torr at 54.3°C and 10.0 torr at 95.3°C. (a) What is its vapor pressure at 25°C? (b) What is the minimum number of liters of air that must passover a sample of the compound at 25°C to vaporize 1.0 mg of it?
Liquid hexanol (C6H13OH) has a normal boiling point of 158 °C and liquid butanol
(C4H,OH) has a normal boiling point of 118 °C.
(a) In which of the two are the intermolecular forces the weakest? hexanol
(b) Which of the two would you expect to have the highest surface tension at 25 °C?
hexanol
hexanol
butanol
Chapter 11 Solutions
Chemistry: Principles and Practice
Ch. 11 - Prob. 11.1QECh. 11 - Prob. 11.2QECh. 11 - Prob. 11.3QECh. 11 - Prob. 11.4QECh. 11 - Prob. 11.5QECh. 11 - Why does a perspiring body achieve greater cooling...Ch. 11 - Prob. 11.7QECh. 11 - Prob. 11.8QECh. 11 - Prob. 11.9QECh. 11 - Prob. 11.10QE
Ch. 11 - Prob. 11.11QECh. 11 - Prob. 11.12QECh. 11 - Prob. 11.13QECh. 11 - Prob. 11.14QECh. 11 - Prob. 11.15QECh. 11 - Prob. 11.16QECh. 11 - Prob. 11.17QECh. 11 - Prob. 11.18QECh. 11 - Prob. 11.19QECh. 11 - Prob. 11.20QECh. 11 - The compounds ethanol (C2H5OH) and dimethyl ether...Ch. 11 - Prob. 11.22QECh. 11 - Prob. 11.23QECh. 11 - An amorphous solid can sometimes be converted to a...Ch. 11 - Prob. 11.25QECh. 11 - Prob. 11.26QECh. 11 - Prob. 11.27QECh. 11 - Prob. 11.28QECh. 11 - Prob. 11.29QECh. 11 - Prob. 11.30QECh. 11 - Prob. 11.31QECh. 11 - Prob. 11.32QECh. 11 - Prob. 11.33QECh. 11 - Prob. 11.34QECh. 11 - Prob. 11.35QECh. 11 - Prob. 11.36QECh. 11 - Prob. 11.37QECh. 11 - Prob. 11.38QECh. 11 - What is the enthalpy change when a 1.00-kg block...Ch. 11 - Prob. 11.40QECh. 11 - Prob. 11.41QECh. 11 - Prob. 11.42QECh. 11 - Prob. 11.43QECh. 11 - Prob. 11.44QECh. 11 - Prob. 11.45QECh. 11 - Prob. 11.46QECh. 11 - Prob. 11.47QECh. 11 - Prob. 11.48QECh. 11 - Identify the kinds of intermolecular forces...Ch. 11 - Prob. 11.50QECh. 11 - Prob. 11.51QECh. 11 - Prob. 11.52QECh. 11 - Prob. 11.53QECh. 11 - Prob. 11.54QECh. 11 - Prob. 11.55QECh. 11 - Prob. 11.56QECh. 11 - Prob. 11.57QECh. 11 - Prob. 11.58QECh. 11 - Prob. 11.59QECh. 11 - Identify the kinds of forces that are most...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Arrange the following substances in order of...Ch. 11 - Prob. 11.63QECh. 11 - Silicon carbide, SiC, is a very hard, high-melting...Ch. 11 - Prob. 11.65QECh. 11 - Calcium oxide consists of a face-centered cubic...Ch. 11 - Prob. 11.67QECh. 11 - Prob. 11.68QECh. 11 - Prob. 11.69QECh. 11 - Prob. 11.70QECh. 11 - Prob. 11.71QECh. 11 - Prob. 11.72QECh. 11 - Prob. 11.73QECh. 11 - Prob. 11.74QECh. 11 - Lithium hydride (LiH) has the sodium chloride...Ch. 11 - Cesium iodide crystallizes as a simple cubic array...Ch. 11 - Palladium has a cubic crystal structure in which...Ch. 11 - Prob. 11.78QECh. 11 - Prob. 11.79QECh. 11 - Prob. 11.80QECh. 11 - Prob. 11.81QECh. 11 - Prob. 11.82QECh. 11 - Prob. 11.83QECh. 11 - Prob. 11.84QECh. 11 - Prob. 11.85QECh. 11 - The coordination number of uniformly sized spheres...Ch. 11 - Prob. 11.87QECh. 11 - Prob. 11.88QECh. 11 - Prob. 11.89QECh. 11 - Prob. 11.90QECh. 11 - Prob. 11.91QECh. 11 - Prob. 11.93QECh. 11 - Prob. 11.94QECh. 11 - A 1.50-g sample of methanol (CH3OH) is placed in...Ch. 11 - Prob. 11.96QECh. 11 - Prob. 11.97QECh. 11 - Prob. 11.98QECh. 11 - Prob. 11.99QECh. 11 - Prob. 11.100QECh. 11 - Prob. 11.103QE
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- What mass (g) of ethanol, CH3CH2OH(), can be vaporized at its boiling point of 78.4 C by transfer of 500. kJ to the liquid? The vapH of ethanol is 38.6 kJ/mol at this temperature.arrow_forwardLiquid hexanol (C6H13OH) has a normal boiling point of 158 °C and liquid butanol (C,H,OH) has a normal boiling point of 118 °C. (a) In which of the two are the intermolecular forces the weakest? hexanol (b) Which of the two would you expect to have the highest surface tension at 25 °C? hexanolarrow_forward(3) Vapor pressure of liquid ethanol is 7291 Pa at 20°C. (a) one student reports that the vapor pressure is 31741 Pa at 52°C. Another student reports it to be 31741 Pa at 502°C. Which of the results is correct? Why? (b) calculate the normal boiling temperature of ethanol (assume Patm=101,325Pa).arrow_forward
- The molecular mass of butanol, C4H9OH, is 74.14; that of ethylene glycol, CH2(OH)CH2OH, is 62.08, yet their boiling points are 117.2 °C and 174 °C, respectively. Explain the reason for the difference.arrow_forwardThe vapor pressure of acetone (C3H,O) at 39.5°C is 400 torr. (a) If the boiling point of acetone is 56.5°C, calculate its enthalpy of vaporization (AH,vap; in kJ/mol). (b) Using calculated (AH,vap and vapor pressure at 39.5, calculate the vapor pressure of acetone at 25°C. (R = 8.314 J/(mol.K))arrow_forwardMethyl salicylate, C3H3O3, the odorous constituent of oil of wintergreen, has a vapor pressure of 1.00 torr at 54.3° C and 10.0 torr at 95.3° C. What is its vapor pressure at 25° ? torrarrow_forward
- Name the phase transition in each of the following situationsand indicate whether it is exothermic or endothermic:(a) When ice is heated, it turns to water. (b) Wetclothes dry on a warm summer day. (c) Frost appears on awindow on a cold winter day. (d) Droplets of water appearon a cold glass of lemonade.arrow_forwardThe phase diagram of a hypothetical substance is (a) Estimate the normal boiling point and freezing point ofthe substance. (b) What is the physical state of the substanceunder the following conditions? (i) T = 150 K, P = 0.2 atm;(ii) T = 100 K, P = 0.8 atm; (iii) T = 300 K, P = 1.0 atm.(c) What is the triple point of the substance?arrow_forwardWhat are the root mean square distances traveled (in one dimension) by a glycine molecule in water and by a sucrose molecule in water at 25°C in 1.0 s? (a) glycine molecule in water (Take D = 1.055 ✕ 10−9 m2·s−1.) (b) sucrose molecule in water (Take D = 5.216 ✕ 10−10 m2·s−1.)arrow_forward
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