The following reaction has the rate law. vo = KA² Two mechanisms have been proposed: Mechanism 1 2A+B - G Mechanism 2 2 A Int B A+ B Int k₂ k.s k₂ Int G Int

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 102CP: Consider a reaction of the type aA products, in which the rate law is found to he rate = k[A]3...
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The following reaction has the rate law. vo =
Two mechanisms have been proposed:
Mechanism 1
Mechanism 2
KA1²
2A+B - G
2 A
Int B
A+ B
Int+ A
k₂
k.s
k₂
k1
k₂
Mechanism 1, where Step 1 is slow, and Step 2 is fast.
Int
G
Mechanism 2, where Step 1 is slow, and Step 2 is fast.
Int
Which mechanism is consistent with the rate law, given the conditions indicated
below?
G
Neither mechanism is consistent with the observed rate law.
Both mechanisms, where Step 1 is a fast, reversible step and Step 2 is slow.
Transcribed Image Text:The following reaction has the rate law. vo = Two mechanisms have been proposed: Mechanism 1 Mechanism 2 KA1² 2A+B - G 2 A Int B A+ B Int+ A k₂ k.s k₂ k1 k₂ Mechanism 1, where Step 1 is slow, and Step 2 is fast. Int G Mechanism 2, where Step 1 is slow, and Step 2 is fast. Int Which mechanism is consistent with the rate law, given the conditions indicated below? G Neither mechanism is consistent with the observed rate law. Both mechanisms, where Step 1 is a fast, reversible step and Step 2 is slow.
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