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4. The "Gibbs Reflective Cycle" be explained. In each phase of the reflective cycle, provide an example.?
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- Explain the "Gibbs Reflective Cycle". Give example in each step of the reflective cycle.The Cavity Ring-Down Spectroscopy (CRDS) technique offers greater sensitivity compared to other conventional spectroscopy techniques. Explain the underlying mechanism of this.Describe the effects of a lethal dose of ionizingradiation at the molecular level. What type of filterwould be used to filter sterilize a heat-sensitive liquid?
- (c) Mössbauer spectroscopy. Discuss briefly the principle of1. What are the 3 important colligative properties discussed in class, give their applications.Sulfamethoxazole is a type of sulfonamide antibiotic. Its absorbance ranges from 250-300 nm in a UV spectrophotometer, which tells that it is in the UV region. What characteristic/s of sulfamethoxazole is responsible for the absorbance in the UV region? Please answer in detail and clearly. Thank you!
- You are stumped for a while, because you really don't want to spend all day running columns, and then having to measure the column fractions with UV-VIS. Your colleague however tells you that it is possible to use the spectrum of the mixture to determine the concentration of cach vitamin in the mixture. (c) Briefly explain why it is possible to use the spectrum of the mixture to determine the concentration of each vitamin in the mixture. Now that you realise that it is possible, you get some information about the molar absorptivities of cach vitamin at cach Amax, and list it in Table 1. Table 1. The molar absorptivities of Vitamins B1 and B6 measured in pure samples of each. E (M' cm') a (nm) Vitamin B1 Vitamin B6 423 5075 240 11280 285 1504 (d)(1) Use the information in Table 1 and the absorbance of the sample mixture at the relevant wavelengths (Figure 1) to determine the concentration of Vitamin B1 in the diluted, prepared sample. (d)(i) Determine the mass of Vitamin B1 in one of…“Atomic absorption spectroscopy (AAS) and UV-Vis spectroscopy is similar in principles”. Do you agree with this statement? Explain briefly.4. Suggest the qualitative test for the compound with molecular formula CeH,Br30. Predict what information from IR and NMR spectra will help you to classify this compound.
- 5. A tissue plasminogen activator (TPA) ophthalmic solution is prepared to con- tain 25 µg/100 μL. (a) Calculate the percentage concentration of TPA in the solution. (b) What volume of a solution containing TPA, 50 mg/50 mL, should be used to prepare each 100 μL of the opthalmic solution? 5. (a) 0.025% w/v TPA (b) 0.025 mL[fifteen] A student ran a TLC plate using 60:40 water:ethanol developer and these were their computed Rf values: Pigment Retention Factor Compund A 0.55 Compund B 0.32 Compund C 0.89 What can you conclude about the polarities of the different components based solely on this result?b) Consider the quenching of an organic fluorescent species with 70 = 6.0 ns and ką = 3.0×10° dm³ mol-1 s-1. Predict the concentration of quencher required to decrease the fluorescence intensity of the organic species to 50% of the unquenched value.