2. Chloroform (CHCI3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCI4) according to the reaction CHCI:(9) + C2(9) D CCL(9) + HCl(g) Several experiments obtained the following data: Initial [CHCI3] (M) Initial [Cl] (M) Initial Rate of Experiment Reaction (M/s). 0.0011 0.014 2.60 x 104 II 0.0011 0.028 5.20 x 104 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.

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Chapter12: Kinetics
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2. Chloroform (CHCI3) is a known anesthetic. It is also used to produce the
refrigerant carbon tetrachloride (CCI4) according to the reaction
CHCI3(9) + Cl2(9) D CCI(9) + HCl(g)
Several experiments obtained the following data:
Initial [CHCI3]
(M)
Initial [Cl2] (M)
Initial Rate of
Experiment
Reaction (M/s)
0.0011
0.014
2.60 x 104
II
0.0011
0.028
5.20 x 104
II
0.0022
0.028
2.08 x 10-3
IV
0.0022
0.014
1.04 x 10-3
Write the rate law expression for this reaction. Determine the value of the rate constant.
Transcribed Image Text:2. Chloroform (CHCI3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCI4) according to the reaction CHCI3(9) + Cl2(9) D CCI(9) + HCl(g) Several experiments obtained the following data: Initial [CHCI3] (M) Initial [Cl2] (M) Initial Rate of Experiment Reaction (M/s) 0.0011 0.014 2.60 x 104 II 0.0011 0.028 5.20 x 104 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.
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