Chloroform (CHCI3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCI4) according to the reaction CHCI3(9) + Cl2(g) CCla(9) + HC(g) Several experiments obtained the following data: Initial (Cl2] (M) Initial [CHCI3] (M) Initial Rate of Experiment Reaction (M/s) 0.0011 0.014 2.60 x 10-4 0.0011 0.028 5.20 x 10-4 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.

Chemistry: Principles and Reactions
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Chapter11: Rate Of Reaction
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Problem 35QAP: Azomethane decomposes into nitrogen and ethane at high temperatures according to the following...
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2. Chloroform (CHCI3) is a known anesthetic. It is also used to produce the
refrigerant carbon tetrachloride (CCCA) according to the reaction
CHCI3(g) + Cl2(g) Cl«(9) + HC(g)
Several experiments obtained the following data:
Initial [CHCI3]
(M)
Initial [Cl2] (M)
Initial Rate of
Experiment
Reaction (M/s)
0.0011
0.014
2.60 x 10-4
II
0.0011
0.028
5.20 x 10-4
II
0.0022
0.028
2.08 x 10-3
IV
0.0022
0.014
1.04 x 10-3
Write the rate law expression for this reaction. Determine the value of the rate constant.
Transcribed Image Text:2. Chloroform (CHCI3) is a known anesthetic. It is also used to produce the refrigerant carbon tetrachloride (CCCA) according to the reaction CHCI3(g) + Cl2(g) Cl«(9) + HC(g) Several experiments obtained the following data: Initial [CHCI3] (M) Initial [Cl2] (M) Initial Rate of Experiment Reaction (M/s) 0.0011 0.014 2.60 x 10-4 II 0.0011 0.028 5.20 x 10-4 II 0.0022 0.028 2.08 x 10-3 IV 0.0022 0.014 1.04 x 10-3 Write the rate law expression for this reaction. Determine the value of the rate constant.
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