Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 8.41PAE
8.41 What is the specific feature of N, O, and F that causes them to play a role in hydrogen bonding?
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A student investigates the physical and chemical properties of various carbon-containing compounds. Thr complete Lewis electron-dot diagrams and boiling points for two compounds, Q and Z, are shown in the following table:
B) Any C — H bond in compound Q is shorter than the S — H bond in compound Z. Explain the reason for this difference using principles of atomic structure.
Which substance in each of the following pairs would you expect to have the higher boiling
point?
(a) Ne or Xe, (b) CO2 or CS2, (c) CH4 or Cl2, (d) F2 or LiF, (e) NH3 or PH3
(a) Ne; (b) CS2; (c) CH4; (d) F2 ; (e) NH3
(a) Xe; (b) CS2; (c) Cl2; (d) LiF ; (e) PH3
O (a) Xe; (b) CS2; (c) Cl2; (d) LiF ; (e) NH3
(a) Xe; (b) CS2; (c) Cl2; (d) F2 ; (e) NH3
(a) Xe; (b) C02; (c) CH4 ; (d) LiF ; (e) PH3
Which member of each of the following pairs of substances would you expect to have a higher boiling
point?
(a) O2 and Cl2, (b) SO2 and CO2, (c) HF and HI
Chapter 8 Solutions
Chemistry for Engineering Students
Ch. 8 - Prob. 1COCh. 8 - • describe the arrangement of atoms in the common...Ch. 8 - • use bind theory to describe bonding in solids.Ch. 8 - Prob. 4COCh. 8 - Prob. 5COCh. 8 - Prob. 6COCh. 8 - Prob. 7COCh. 8 - • explain the connection between intermolecular...Ch. 8 - Prob. 9COCh. 8 - Prob. 10CO
Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Prob. 8.10PAECh. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.14PAECh. 8 - Prob. 8.15PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.19PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.21PAECh. 8 - Prob. 8.22PAECh. 8 - Prob. 8.23PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.26PAECh. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - Prob. 8.29PAECh. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.42PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.44PAECh. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.49PAECh. 8 - Prob. 8.50PAECh. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.53PAECh. 8 - Prob. 8.54PAECh. 8 - Prob. 8.55PAECh. 8 - Prob. 8.56PAECh. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Prob. 8.60PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.62PAECh. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Prob. 8.69PAECh. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - Prob. 8.73PAECh. 8 - Prob. 8.74PAECh. 8 - 8.75 Using pentagons, draw arrangements that...Ch. 8 - 8.76 Using circles, draw regular two-dimensional...Ch. 8 - 8.77 What is the difference between a bonding...Ch. 8 - Prob. 8.78PAECh. 8 - 8.79 Most gaseous compounds consist of small...Ch. 8 - 8.80 Why are dipole—dipole forces typically...Ch. 8 - 8.81 Carbon tetrachloride (CCl4) is a liquid at...Ch. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 Cryolite (Na3AlF6) is used in refining...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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- Which of the following liquids is held together by hydrogen bonding? i) methano l ii) petrol iii) glycerol iv) ethanal (acetaldehyde) Using your knowledge of Lewis structures, deduce the structure of the cation PF4+. What is its true shape and F-P-F bond angle?arrow_forwardWhich substance in each of the following pairs would you expect to have the higher boiling point? (a) Ne or Xe, (b) CO, or CSz, (e) CH4 or C, (d) Fz or LiF, (e) NH; or PH, O (a) Xe; (b) CS2: (e) Cl; (d) F2; (e) NH3 O (a) Xe; (b) CS;; (c) Ch; (d) LiF; (e) PH3 O (a) Xe; (b) CS2; (c) Ch; (d) LiF; (e) NH3 O (a) Ne; (b) CS2; (c) CH; (d) F2; (e) NH3 O (a) Xe; (b) CO2: (e) CH4: (d) LiF: (e) PH3arrow_forwardWhy do only two H bonds form between A and T (compared with three forC and G)?arrow_forward
- Define valency by taking examples of silicon and sulphur?arrow_forwardQuartz crystals are made of silicon dioxide. What is the molecular geometry of silicon dioxide? (*hint* sketch the molecule before answering) O Linear O Bent O Trigonal Pyramidal O Tetrahedralarrow_forward7. Explain why HBr is a polar molecule, but H2 and Br2 are not. 8.Predict what type of solid will be formed in each of the following: boron and nitrogen francium and iodine carbon and sulphur silicon dioxide (quartz) copper sulphate and zincarrow_forward
- what type of lattice does the ionic compound Ba3N2 belong?arrow_forward8.6 At 25°C, B = -42 cm³/mol for CH, and B = -732 cm³/mol for n-C,H10. For a mixture of 0.0300 mol of CH, and 0.0700 mol of n-C,H10 at 25°C in a 1.000-L vessel, calculate the pressure using the virial equation and (a) the approximation B12 = (B, + B,); (b) the fact that for this mixture, B = -180 cm³/mol. Compare the results with the ideal-gas-equation %3D %3D 12 result.arrow_forwardThe structures of molecules that are held together by v bonds can be diagrammed by Lewis electron-dot structures.arrow_forward
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