Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 7, Problem 7.2P

(a)

Interpretation Introduction

Interpretation:

The de Broglie wavelength for electron accelerated through 1V and also the momentum for the electrons has to be calculated.

Concept Introduction:

Work function: Work function of a metal is measure of strength of electrons is held in a metal atom.

=KE+ϕ here,ϕ = work functionKE = kinetic energyh = Planck’s constant ν= frequency

Energy can be in the form of kinetic energy or potential energy.  Kinetic energy is the energy associated with motion.

Ek=12mv2 here,m - Mass in kilogramsv - Velocity in meters per second

Louis de Broglie in 1923 rationalized that when light shows particle aspects, then particles of matter display properties of waves under definite circumstances.

λ=hmυp = mυ Hence λ=hp h is Planck’s constant (6.626×1034J.s) which relates energy and frequencyυis the speed of particlem is the mass of particle λis the wavelengthp is the momentum

The above equation is called de Broglie relation.

(a)

Expert Solution
Check Mark

Explanation of Solution

Given:

10MeV Particle accelerator

The electron wavelength present in given accelerator is determined by using kinetic energy equation.

Ek=12mev2p=mevEk=p22mep=2meEk

p=2meEk 1

Substituting equation 1 in de Broglie equation

p=2meEk 1λ=hpdeBroglieequation=h2meEk 2

For accelerated electron energy is equal to eΔϕ. Then equation 2 becomes,

=h2meEk 2=h2meϕ [Ek=ϕ]λ=h2meϕ

λ=h2meϕ=6.626×10-342(9.109×1031)(1.602×1019)(1)×JskgCeV [1J=1CV=1kgm2s-2] =1.23×109m=1.23nm [1nm=10-9m]

p=hλ=6.626×10-341.23×109×Jsm [1J=1CV=1kgm2s-2] =5.4×1025kgms-1

(b)

Interpretation Introduction

Interpretation:

The de Broglie wavelength for electron accelerated through 1kV and also the momentum for the electrons has to be calculated.

Concept Introduction:

Work function: Work function of a metal is measure of strength of electrons is held in a metal atom.

=KE+ϕ here,ϕ = work functionKE = kinetic energyh = Planck’s constant ν= frequency

Energy can be in the form of kinetic energy or potential energy.  Kinetic energy is the energy associated with motion.

Ek=12mv2 here,m - Mass in kilogramsv - Velocity in meters per second

Louis de Broglie in 1923 rationalized that when light shows particle aspects, then particles of matter display properties of waves under definite circumstances.

λ=hmυp = mυ Hence λ=hp h is Planck’s constant (6.626×1034J.s) which relates energy and frequencyυis the speed of particlem is the mass of particle λis the wavelengthp is the momentum

The above equation is called de Broglie relation.

(b)

Expert Solution
Check Mark

Explanation of Solution

Given:

10MeV Particle accelerator

The electron wavelength present in given accelerator is determined by using kinetic energy equation.

Ek=12mev2p=mevEk=p22mep=2meEk

p=2meEk 1

Substituting equation 1 in de Broglie equation

p=2meEk 1λ=hpdeBroglieequation=h2meEk 2

For accelerated electron energy is equal to eΔϕ. Then equation 2 becomes,

=h2meEk 2=h2meϕ [Ek=ϕ]λ=h2meϕ

λ=h2meϕ=6.626×10-342(9.109×1031)(1.602×1019)(1×103)×JskgCeV [1J=1CV=1kgm2s-2] =3.9×1011m=39×1012m=39nm [1pm=10-11m]

p=hλ=6.626×10-3439×1012×Jsm [1J=1CV=1kgm2s-2] =1.7×1023kgms-1

(c)

Interpretation Introduction

Interpretation:

The de Broglie wavelength for electron accelerated through 100kV and also the momentum for the electrons has to be calculated.

Concept Introduction:

Work function: Work function of a metal is measure of strength of electrons is held in a metal atom.

=KE+ϕ here,ϕ = work functionKE = kinetic energyh = Planck’s constant ν= frequency

Energy can be in the form of kinetic energy or potential energy.  Kinetic energy is the energy associated with motion.

Ek=12mv2 here,m - Mass in kilogramsv - Velocity in meters per second

Louis de Broglie in 1923 rationalized that when light shows particle aspects, then particles of matter display properties of waves under definite circumstances.

λ=hmυp = mυ Hence λ=hp h is Planck’s constant (6.626×1034J.s) which relates energy and frequencyυis the speed of particlem is the mass of particle λis the wavelengthp is the momentum

The above equation is called de Broglie relation.

(c)

Expert Solution
Check Mark

Explanation of Solution

Given:

10MeV Particle accelerator

The electron wavelength present in given accelerator is determined by using kinetic energy equation.

Ek=12mev2p=mevEk=p22mep=2meEk

p=2meEk 1

Substituting equation 1 in de Broglie equation

p=2meEk 1λ=hpdeBroglieequation=h2meEk 2

For accelerated electron energy is equal to eΔϕ. Then equation 2 becomes,

=h2meEk 2=h2meϕ [Ek=ϕ]λ=h2meϕ

λ=h2meϕ=6.626×10-342(9.109×1031)(1.602×1019)(100×103)×JskgCeV [1J=1CV=1kgm2s-2] =3.88×1012m=3.88pm [1pm=10-12m]

p=hλ=6.626×10-343.88×1012×Jsm [1J=1CV=1kgm2s-2] =1.71×1022kgms-1

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