Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 7, Problem 17PS
Interpretation Introduction
Interpretation:
The effective nuclear charge (Z*) has to explained for given Lithium (Li) to fluorine (F) atoms.
Concept Introduction:
Nuclear charge (Z*): The effective nuclear charge generally denoted by (Zeff or Z*) it is the net positive charge experienced by an electron in a multi-electron atom. This word “effective” is used because the shielding effect of negatively charged electron prevents higher orbital electrons experience the full nuclear charge.
Increase and decrease electro negativity: The less vacancy electrons an atoms has the least it will gain of electrons. Moreover the
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Q1.
This question is about atomic structure.
(a) Write the full electron configuration for each of the following species.
CH
Fe2+
(b) Write an equation, including state symbols, to represent the process that occurs
when the third ionisation energy of manganese is measured.
(c)
State which of the elements magnesium and aluminium has the lower first ionisation
energy
Explain your answer.
(d) A sample of nickel was analysed in a time of flight (TOF) mass spectrometer. The
sample was ionised by electron impact ionisation. The spectrum produced showed
three peaks with abundances as set out in the table.
m/z
Abundance /%
58
61.0
60
29.1
61
9.9
Give the symbol, including mass number, of the ion that would reach the detector
first in the sample.
Calculate the relative atomic mass of the nickel in the sample.
Give your answer to one decimal place.
Page 2 of 12
Symbol of ion
Relative atomic mass
1. An element has the following electronic configuration: [Kr]4d105s25p4(a) What period does it belong to?(b) What is its group number? (Use group numbers from 1 to 18)(c) What kind of element is it? (Main group metal, transition metal, metalloid, nonmetal?)(d) How many unpaired electrons are there in an atom of this element?
3. (a) Which of the following atoms or ions is diamagnetic?Li+ Ni2+ Al Fe2+ Mn3+(b) Which of the following atoms or ions is paramagnetic?C4- S4+ V4+ Se2- Ge4+
Which of the following elements is expected to have the highest SECOND IONIZATION ENERGY: (A) Be (B) Ca (C) Mg (D) Na
Chapter 7 Solutions
Chemistry & Chemical Reactivity
Ch. 7.3 - (a) What element has the configuration...Ch. 7.3 - Write one possible set of quantum numbers for the...Ch. 7.3 - Using the periodic table and without looking at...Ch. 7.4 - Prob. 7.4CYUCh. 7.5 - Without looking at the figures for the periodic...Ch. 7.6 - The most common oxidation state of a rare earth...Ch. 7.6 - Prob. 1.2ACPCh. 7.6 - Prob. 1.3ACPCh. 7.6 - Use the atomic radii of scandium, yttrium,...Ch. 7.6 - Prob. 1.5ACP
Ch. 7.6 - Prob. 1.6ACPCh. 7.6 - Give the electron configurations for iron and the...Ch. 7.6 - Prob. 2.2ACPCh. 7.6 - Prob. 2.3ACPCh. 7.6 - Prob. 2.4ACPCh. 7 - Write the electron configurations for P and CI...Ch. 7 - Write the electron configurations for Mg and Ar...Ch. 7 - Using spdf notation, write the electron...Ch. 7 - Using spdf notation, give the electron...Ch. 7 - Prob. 5PSCh. 7 - Prob. 6PSCh. 7 - Use noble gas and spdf notations to depict...Ch. 7 - The lanthanides, once called the rare earth...Ch. 7 - Prob. 9PSCh. 7 - Prob. 10PSCh. 7 - What is the maximum number of electrons that can...Ch. 7 - What is the maximum number of electrons that can...Ch. 7 - Depict the electron configuration for magnesium...Ch. 7 - Depict the electron configuration for phosphorus...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 17PSCh. 7 - Which of the following statements correctly...Ch. 7 - Prob. 19PSCh. 7 - Prob. 20PSCh. 7 - Using orbital box diagrams, depict an electron...Ch. 7 - Prob. 22PSCh. 7 - Prob. 23PSCh. 7 - Using orbital box diagrams and noble gas notation,...Ch. 7 - Manganese is found as MnO2 in deep ocean deposits....Ch. 7 - One compound found in alkaline batteries is NiOOH,...Ch. 7 - Prob. 27PSCh. 7 - Arrange the following elements in order of...Ch. 7 - Prob. 29PSCh. 7 - Prob. 30PSCh. 7 - Which of the following groups of elements is...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Compare the elements Na, Mg, O, and P. (a) Which...Ch. 7 - Compare the elements B. Al, C, and Si. (a) Which...Ch. 7 - Explain each answer briefly. (a) Place the...Ch. 7 - Explain each answer briefly. (a) Rank the...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Explain why the photoelectron spectra of hydrogen...Ch. 7 - Sketch the major features (number of peaks and...Ch. 7 - These questions are not designated as to type or...Ch. 7 - The deep blue color of sapphires comes from the...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 44GQCh. 7 - Prob. 45GQCh. 7 - Prob. 46GQCh. 7 - Which of the following is not an allowable set of...Ch. 7 - A possible excited state for the H atom has an...Ch. 7 - The magnet in the following photo is made from...Ch. 7 - Name the element corresponding to each...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 52GQCh. 7 - Answer the questions below about the elements A...Ch. 7 - Answer (he following questions about the elements...Ch. 7 - Which of the following ions are unlikely to be...Ch. 7 - Prob. 56GQCh. 7 - Answer each of the following questions: (a) Of the...Ch. 7 - Prob. 58GQCh. 7 - Prob. 59GQCh. 7 - Two elements in the second transition series (Y...Ch. 7 - Prob. 61GQCh. 7 - The configuration of an element is given here. (a)...Ch. 7 - Answer the questions below about the elements A...Ch. 7 - Answer the questions below concerning ground state...Ch. 7 - Nickel(II) formate [Ni(HCO2)2] is widely used as a...Ch. 7 - Spinets are solids with the general formula M2+...Ch. 7 - The following questions use concepts from this and...Ch. 7 - Which ions in the following list are not likely to...Ch. 7 - Answer the following questions about first...Ch. 7 - The ionization of the hydrogen atom can be...Ch. 7 - Compare the configurations below with two...Ch. 7 - Prob. 72SCQCh. 7 - Write electron configurations to show the first...Ch. 7 - Prob. 74SCQCh. 7 - (a) Explain why the sizes of atoms change when...Ch. 7 - Which of the following elements has the greatest...Ch. 7 - Prob. 77SCQCh. 7 - Prob. 78SCQCh. 7 - The energies of the orbitals in many elements have...Ch. 7 - The ionization energies for the removal of the...Ch. 7 - Using your knowledge of the trends in element...Ch. 7 - Prob. 82SCQCh. 7 - Prob. 83SCQCh. 7 - Prob. 84SCQCh. 7 - Thionyl chloride. SOCl2, is an important...Ch. 7 - Prob. 86SCQCh. 7 - Slaters rules are a way to estimate the effective...
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- 2-89 Assume that a new element has been discovered with atomic number 117. Its chemical properties should be similar to those of astatine (At). Predict whether the new element’s ionization energy will be greater than, the same as, or smaller than that of: (a)At (b)Raarrow_forwardArrange in order of increasing nonmetallic character. (Use the appropriate <, =, or > symbol to separate substances in the list.) (a) the Period 4 elements V, Ge, and K (b) the Group 5A elements N, As, and Bi Arrange in order of increasing atomic size. (Use the appropriate <, =, or > symbol to separate substances in the list.) (a) the Period 3 elements Mg, Si, and Ar (b) the Group 2A elements Ca, Ba, and Srarrow_forwardQ2. This question is about the periodicity of the Period 3 elements. (a) State and explain the general trend in first ionisation energy across Period 3. Give one example of an element which deviates from the general trend in first (b) ionisation energy across Period 3. Explain why this deviation occurs. Page 3 of 12 (c) The table shows successive ionisation energies of an element Y in Period 3. lonisation number 1 2 3 4 5 6 7 8 lonisation energy kJ mol- 1000 2260 3390 4540 6990 8490 27 100 31 700 Identify element Y Explain your answer using data from the table. (d) Identify the Period 3 element that has the highest melting point. Explain your answer by reference to structure and bonding.arrow_forward
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- Write the ground-state electron configurations of the following ions. (a) Li+ (b) N3− (c) In3+ (Use the noble gas core electron configuration in your answer.) (d) Tl+ (Use the noble gas core electron configuration in your answer.)arrow_forward15. (a) b) Identify the element that is described by the following information. Refer to a periodic table if necessary. It is a group 14 (III A) metalloid in the 3rd period. It is a group 15 (VA) metalloid in the 5th period. It is the other metalloid in group 15 (VA). d) It is a halogen that exists in the liquid state at room temperature. 16. What is the relationship between electron arrangement and the organization of elements in the periodic table?arrow_forwardAn element has the following electronic configuration: [Kr]4d105s25p2(a) What period does it belong to?(b) What is its group number? (Use group numbers from 1 to 18)(c) What kind of element is it? (Main group metal, transition metal, metalloid, nonmetal?)(d) How many unpaired electrons are there in an atom of this element?arrow_forward
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