Chapter 6, Problem 6.44SP

(a)

Interpretation Introduction

Interpretation:

The perspective structures or Fischer projections for the substitution product of the given reaction is to be shown.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction.

The nucleophilic reaction that contains only a substrate as a reactant, and not a nucleophile, that is, a unimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}1$ reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(b)

Interpretation Introduction

Interpretation:

The perspective structures or Fischer projections for the substitution product of the given reaction is to be shown.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction.

The nucleophilic reaction that contains only a substrate as a reactant, and not a nucleophile, that is, a unimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}1$ reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(c)

Interpretation Introduction

Interpretation:

The perspective structures or Fischer projections for the substitution product of the given reaction is to be shown.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction.

The nucleophilic reaction that contains only a substrate as a reactant, and not a nucleophile, that is, a unimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}1$ reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.