Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 43P
Which of the following have an asymmetric center?
CHBr2Cl CH2FCl CH3CHCl2 CHFBrCl CH3CH2CHClCH3
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CH3
fo
OH
CH₂CH₂Br
(H3C)3C.
HO
CO₂H
H₂C=C-
C=CH
-CH(CH₂CH3)2
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3
(numbers indicate the IUPAC
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Chapter 4 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.1 - Prob. 6PCh. 4.2 - Prob. 7PCh. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10PCh. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.
Ch. 4.3 - Prob. 13PCh. 4.4 - Prob. 14PCh. 4.5 - Prob. 16PCh. 4.6 - Prob. 17PCh. 4.7 - Assign relative priorities to the groups or atoms...Ch. 4.7 - Name the following:Ch. 4.7 - Prob. 22PCh. 4.7 - Draw a perspective formula for each of the...Ch. 4.8 - Prob. 24PCh. 4.8 - Prob. 27PCh. 4.9 - Prob. 28PCh. 4.9 - Prob. 29PCh. 4.9 - Prob. 30PCh. 4.10 - Prob. 31PCh. 4.10 - Prob. 32PCh. 4.10 - Prob. 33PCh. 4.11 - Prob. 34PCh. 4.11 - a. Draw the stereoisomers of...Ch. 4.11 - Prob. 37PCh. 4.11 - Prob. 38PCh. 4.12 - Which of the following compounds has a...Ch. 4.12 - Draw all the stereoisomers for each of the...Ch. 4.12 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Which of the following have an asymmetric center?...Ch. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Of all the possible cyclooctanes that have one...Ch. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Draw the stereoisomers of 2,4-dichlorohexane....Ch. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Prob. 62PCh. 4 - Draw structures for each of the following: a....Ch. 4 - Prob. 64PCh. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 66PCh. 4 - Prob. 67PCh. 4 - Prob. 68PCh. 4 - Chloramphenicol is a broad-spectrum antibiotic...
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- Which of the following molecules are chiral and which are achiral? Cl CH3CHBr Cl CICH₂CH₂Br H CH3 CH3CHBr Clarrow_forwardAn example of a chiral center is a carbon that bears 4 different groups, and therefore has no symmetry. Select ALL of the molecules that contain a chiral center. CI 요 Br 8 Brarrow_forwardDetermine the absolute configuration at the chiral center in each of the following molecules. CH3 H. CHO CH3 CH,co,H CH2CH CH3 CO2H CI H. CH NCH3 CH 1 3. 12 3 RRS OSRR OSSR OSRS RRRarrow_forward
- Encircle the chiral center/s in each molecule. Assign R or S configurations for each chiral center. No need to name the molecule. Br NH2 NH2 H3C H3C *CH3 CH3 ноarrow_forwardDetermine if this molecule is chiral, and also identify any chiral centers. H3C a H₂ C b ΤΟ H₂ C d 8 CH3 CH f h C H₂ i CH3arrow_forwardCymbalta (shown below) is an antidepressant. How many asymmetric centers are present in this structure? SIN N.arrow_forward
- 2. Assign the R or S configuration to each chiral center in the molecules below. CH2CH2B. CH3 .CO2H (H3C)3C. C=CH HO CH,F H,C=G+CH(CH,CH3)2 CH2CH,CH3 HO H C(CH3)3 ОН CH,CH,Br F"CH2Br 3 4 (numbers indicate the IUPAC numbering)arrow_forwardwhich of the following structures is different from the other three. Show your reasoning. H CH3CH₂ Br H $$$**** CH3 H A 5 CH3 CH3CH2 Saml 3 Br CH3 HO CH3 B H Br- CH3CH2 C CH3 H What is the configuration of the two chiral centers in the following molecule? 1 =CH H3C D Br CH₂CH3arrow_forwardWhich of the pairs of compounds are enantiomers (optical isomers)? H3C H OH ☐ H₂C-CH₂ CH3CH₂CH₂CHCH3 H3C SH III. C. H H CH₂ Br -CH3 HO H3C H3C- H Br SH CH3CH₂CHCH₂CH3 H₂C- G|||| CH3 H3C- ** H CH₂ H CH3 H CH3arrow_forward
- What is the 3D representation of these chemicals BeCl2 NCl3 BrCl3 BrF5arrow_forward1. Complete the following table: Position numbers and Compound Parent Chain (Name) IUPAC name name of substituentsarrow_forwardIdentify e absolute configurations of all chiral centers in the following compounds. H CH3 H CI HO CH3 H, Bì Harrow_forward
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