(a) Interpretation: The formula for the carbonate salt of [ Fe(H 2 O) 6 3 + ] complex needs to be determined. Concept introduction: Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 1

Question

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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The formation constant of a complex ion [M(NH3)4]2+(aq) is 8.8E8. If a solution is prepared by adding 0.4 mol of [M(NH3)4]Cl2 to 525.0 mL of water, what is the equilibrium concentration of free M2+(aq) ions? Include 3 significant figures

2. When a metal complex ion is formed in solution, what are the metal ion and ligands acting as? * O a) The ligand is a Lewis base, and the metal ion is its conjugate acid. O b) The metal ion is a Lewis acid, and the ligand is its conjugate base. c) The metal ion acts as a Lewis base, and the ligand acts as a Lewis acid d) The ligand is a Lewis base, and the metal ion is its conjugate acid.

The formation constant of a complex ion [M(NH3)4]2+(aq) is 1.8E8. If a solution is prepared by adding 0.3 mol of [M(NH3)4]Cl2 to 850.0 mL of water, what is the equilibrium concentration of free M2+(aq) ions?

Answer 2

Question

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 3

Question

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 4

Question

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 5

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 6

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 7

Chapter 19, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The formula for the carbonate salt of [Fe(H2O)63+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The formula for the barium salt of [Pt(NH3)(Br)3−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The formula for the barium salt of [V(en)(Cl)42−] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The formula for the carbonate salt of [Au(CN)2+] complex needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains that the formula for the carbonate salt of left[Fe(H_2TextO)] needs to be determined. A ligand is an atom

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Chapter 19 Solutions