a) Ethyl 1-ethylpropyl ether
Interpretation:
The structure of ethyl 1-ethylpropyl ether is to be drawn.
Concept introduction:
Simple ethers are with no other
To draw:
The structure of ethyl 1-ethylpropyl ether.
b) Di (p-chlorophenyl) ether
Interpretation:
The structure of di (p-chlorophenyl) ether is to be drawn.
Concept introduction:
Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.
To give:
The structure of di(p-chlorophenyl) ether.
c) 3, 4-Dimethoxybenzoic acid
Interpretation:
The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.
Concept introduction:
Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.
To give:
The structure of 3, 4-dimethoxybenzoic acid.
d) Cyclopentyloxycyclohexane
Interpretation:
The structure of cyclopentyloxycyclohexane is to be drawn.
Concept introduction:
Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.
To give:
The structure of cyclopentyloxycyclohexane.
e) 4-Allyl-2-methoxyphenol (eugenol)
Interpretation:
The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.
Concept introduction:
Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.
To give:
The structure of 4-allyl-2-methoxyphenol (eugenol).
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Chapter 18 Solutions
Organic Chemistry
- Predict which member of each group is most soluble in water, and explain the reasons for your predictions.(a) butan-1-ol, pentan-1-ol, or propan-2-ol(b) chlorocyclohexane, cyclohexanol, or cyclohexane-1,2-diol(c) phenol, cyclohexanol, or 4-methylcyclohexanolarrow_forwardDraw structural formulas for these compounds. (a) 1-Bromo-2-chloro-4-ethylbenzene (b) 4-Bromo-1,2-dimethylbenzene (c) 2,4,6-Trinitrotoluene (d) 4-Phenyl-1-pentene (e) p-Cresol (f) 2,4-Dichlorophenolarrow_forwardDraw structures corresponding to the following IUPAC names: (a) 3-Methylbutanal (b) 3-Methylbut-3-enal (c) 4-Chloropentan-2-one (d) Phenylacetaldehyde (e) 2,2-Dimethylcyclohexanecarbaldehyde (f ) Cyclohexane-1,3-dionearrow_forward
- Describe how would you distinguish the following pairs, (a) Benzene and cyclohexane (b) Phenol and toluene (c) Phenol and benzoic acid (d) methanol and isopropyl alcoholarrow_forwardWrite the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forwardEthers (general formula R—O—R)have many important uses. Until recently,methyl tert-butyl ether (MTBE, right)was used as an octane booster and fueladditive for gasoline. It increases the oxy-gen content of the fuel, which reducesCO emissions. MTBE is synthesized bythe catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint:Alcohols add to alkenes similarly to the way water does.)(b) If the government required that auto fuel mixtures contain2.7% oxygen by mass to reduce CO emissions, how many gramsof MTBE would have to be added to each 100. g of gasoline?(c) How many liters of MTBE would be in each liter of fuel mix-ture? (The density of both gasoline and MTBE is 0.740 g/mL.)(d) How many liters of air (21% O₂ by volume) are needed at24C and 1.00 atm to fully combust 1.00 L of MTBE?arrow_forward
- Write structural formulas for the following compounds (includes both old- and new-style names).(a) 2-octyne (b) ethylisopentylacetylene (c) ethynylbenzene(d) cyclohexylacetylene (e) 5-methyl-3-octyne (f) trans-3,5-dibromocyclodecynearrow_forwardDraw structures corresponding to the following IUPAC names: (a) p-Bromochlorobenzene (c) m-Chloroaniline (b) p-Bromatolvene (d) 1-Chloro-3,5-dimethylbenzenearrow_forwardDraw a structural formula for each alcohol. (a) Isopropyl alcohol (b) Propylene glycol (c) 5-Methyl-2-hexanol (d) 2-Methyl-2-propyl-1,3-propanediol (e) 1-Octanol (f) 3,3-Dimethylcyclohexanolarrow_forward
- Give an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).arrow_forward(b) NABH, CH3 COCH,CH3 CH3CH2OH (c)arrow_forwardShow the chemical reaction on how to convert cyclopentene into these compounds. (a) 1,2-dimethylcyclopropane (b) Cyclopentanol (c) Iodocyclopentane (d) Cyclopentane.arrow_forward
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