Concept explainers
Interpretation:
On the basis of aromaticity theory, the compounds A and B are different and the compounds C and D are the same is to be stated.
Concept introduction:
If a compound is aromatic then it has to follow certain rules. A compound that is cyclic, planar, completely conjugated and follows
If a compound is antiaromatic it has some characteristics features such as they are cyclic, nonplanar, completely conjugated compounds. They do not follow Huckel’s
Want to see the full answer?
Check out a sample textbook solutionChapter 15 Solutions
Organic Chemistry
- Explain why C is aromatic.arrow_forwardWhen is a molecule aromatic? Explain?arrow_forwardPyrene has been determined experimentally to be aromatic. At first glance, however, its structure appears to break Hückel’s rule. How so? Can you explain why pyrene exhibits aromaticity?Hint: What are the characteristics of the π system on the periphery of the molecule?arrow_forward
- Question: Describe the concept of "aromaticity" as it pertains to organic chemistry. How does the concept of aromaticity explain the unusual stability of benzene, and how does it apply to heterocyclic compounds?arrow_forward(a) Draw an energy diagram for the cyclopropenyl MOs. (The polygon rule is helpful.) Label each MO as bonding, nonbonding, or antibonding, and add the nonbonding line. Notice that it goes through the approximate average of the MOs.(b) Add electrons to your energy diagram to show the configuration of the cyclopropenyl cation and the cyclopropenyl anion. Which is aromatic and which is antiaromatic?arrow_forwardSome of the following compounds show aromatic properties, and others do not. Predict which ones are likely to be aromatic, and explain why they are aromatic or not. a) b)arrow_forward
- (a) Which of the following has lone pair on O atom that is part of aromaticity? (b) Which lacks complete cyclic conjugation? (c) Which does not follow the Huckel rule?arrow_forward3. What are the factors that confer Aromaticity to an organic molecule?arrow_forwardQuestion: Theoretical Question: Explain the concept of aromaticity in organic chemistry and provide an example of a molecule that limit the conventional rules of aromaticity.arrow_forward
- Which structure is not aromatic? Please explain.arrow_forwardQuestion: Explain the concept of aromaticity in organic chemistry and how it relates to the stability of aromatic compounds.arrow_forwardA) For each molecule, write # of pi electrons in the cyclic conjugated system (which is assumed planar) B) Circle the aromatic onesarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning