Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 14, Problem 14.44E
Describe the products that result when hydrogen
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Define three basic kinds of organic reactions ?
Mark the correct statements about the structural features of alkenes and alkynes. *
A- Free rotation is not possible around a double or triple bond.
B- A triple bond is shorter and stronger than a double bond.
C- A pi-bond can only form by overlap of p-orbitals on adjacent atoms if these atoms are from the same element.
D- The pi-bond in an alkene is weaker than the sigma bond because the sideways overlap of p-orbitals is less than the head-to-head overlap of sp² hybrid orbitals.
E- All the bond angles in an alkyne are 180°.
Alkoxy radicals (R¬O # ) are generally more stable than alkyl (R # ) radicals. Write an equation showing an alkyl free radical (from burning gasoline) abstracting a hydrogen atom from tert-butyl alcohol, (CH 3)3COH. Explain why tert-butyl alcohol works as an antiknock additive for gasoline.
Chapter 14 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forward2. Draw the mechanism of the bromination of acetylene: 3. Draw the structures of the following: a. 3-bromo-3,4-dimethyl-1-hepten-5-yne b. Acetylene c. 1-ethynyl-2-methylcyclohexanearrow_forwardDefine the Properties of Alkyl Halides ?arrow_forward
- How does the structure of an alcohol differ from an ether? Describe how an aldehyde differs in structure from a ketone. Thiols are compounds which resemble alcohols, except that the oxygen atom is replaced by a sulfur atom. Draw the analogous thiol for the four carbon alcohol in Table 1. Describe the structural difference between carboxylic acids and esters. Are ethers polar molecules? Would you expect ethers to have higher or lower boiling points than alkanes (circle one)? Explain. Pentane (an alkane) has a boiling point of 36 °C. Does the data agree with your prediction? explain why this could be the casearrow_forwardConsider the alkene shown below. Which of the labeled structures corresponds to a geometric isomer of the structure? B C O None of the options are a geometric isomer of the structure. O C O A OOOO oarrow_forwardIs the reaction between an alkene and a halogen a substitution reaction(displacement reaction) or another reaction? Explain the reaction mechanism by giving an example.arrow_forward
- 1. Most margarines have been hydrogenated to maintain a soft, homogeneous mixture. While the product is easy to spread, this has made the product an unhealthy choice. A hydrogenation reaction is used to convert an alkene to an alkane. a carboxylic acid to an aldehyde. an alkene to a ketone an aromatic hydrocarbon to a linear hydrocarbonarrow_forwardExcess bromine gas is added to ethyne. The product of this reaction is: 1,1,2,2-tetrabromoethane O 1,2-dibromoethene 1,1-dibromoethane O 1,2-dibromoethanearrow_forwardIs the reaction between an alkene and a halogen a substitution reaction or some other reaction? Explain the reaction mechanism by giving an example.arrow_forward
- H8. please provide real life applications for following chemical reaction. as well please provide a few example about how to use this reaction in day-to-day life. Reaction: 2-chloro-2-methylpropane + H2O → 2-methylpropan-2-ol + HClarrow_forwardD. Ethene 73. The reagent KMN04 is used to completely oxidize acetylene. What is an expected property of the last oxidized form of acetylene? A. It will be soluble in hexane. B. It will exhibit acidic properties. C. It will form precipitate with NaCl. D. It will ionize into carbon and hydrogen. 74. As the molecular weight of alkenes increases, the boiling points also increase. Which of the following factors is best associated to this trend? A. Geometric isomerism B. Surface area C. Dipole interaction D. Structural isomerism 75. Which among the following compounds has the most electronegative carbon in its structure? A. Butyne B. Benzene C. Cyclobutane D. Benzaldehyde 76. Identify the SYSTEMATIC name of the molecule that is illustrated in this item, A. 2,4,6-trinitrotoluene B. 2-methyl-1,3,5-nitrobenzene C. 1-methyl-1,3,5-trinitrobenzene D. 1,3,5-trinitrotoluene CH3 NO2 O2N NO2 77 Identify the SYSTEMATIC name of the molecule that is illustrated in this item. A 1-methylbenzenesulfonic…arrow_forwardThis type of hydrocarbons contain at least one double or triple bond. Unsaturated hydrocarbons Saturated hydrocarbons Polyunsaturated hydrocarbons O Supersaturated hydrocarbons The most acidic among the hydrocarbons. Alkynes Alkenes Alkanes Arenes The number of secondary carbon(s) in this compound. CH3 CH,-C CHCH, CH3 CIarrow_forward
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