How the 13 C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers. Interpretation: How the 13 C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated. Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

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Answer 1

Question

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

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Shown below are carbon NMR spectra for various isomers of C5H11Br. Assign structures for the compound that would produce each spectrum.

The functional groups in an organic compound can frequently be deduced from its infrared absorption spectrum. A compound containing C, H, and O exhibits broad absorption at 3450 cm-1 (m) and an intense band at 1725, plus a band at 1100 cm-1 (m).Relative absorption intensity: (s)=strong, (m)=medium, (w)=weak. What functional class(es) does the compound belong to? List only classes for which evidence is given here. Attach no significance to evidence not cited explicitly.Do not over-interpret exact absorption band positions. None of your inferences should depend on small differences like 10 to 20 cm-1. The functional class(es) of this compound is(are)fill in the blank 1.(Enter letters from the table below, in any order, with no spaces or commas.) a. alkane (List only if no other functional class applies.) b. alkene h. amine c. terminal alkyne i. aldehyde or ketone d. internal alkyne j. carboxylic acid e. arene k. ester f. alcohol l. nitrile g. ether

ii) How are the spectroscopic techniques useful in the structural elucidation of following organic molecules

Answer 2

Question

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

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Answer 3

Question

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

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Answer 4

Question

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

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Answer 5

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 6

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 7

Chapter 13, Problem 13.51SP

(a)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be stated.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 8

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 9

(b)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 10

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 11

(c)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 12

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 13

(d)

Interpretation Introduction

To determine: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

Interpretation: How the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers is to be determined.

Concept introduction: NMR spectroscopy is a technique used to determine a unique structure of the compound. It identifies the carbon-hydrogen bonding of an organic compound. A hydrogen atom is called as a proton in the NMR spectroscopy.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.5A - In a 300-MHz spectrometer, the protons in...Ch. 13.5B - Prob. 13.2P Ch. 13.6 - Determine the number of different kinds of protons...Ch. 13.6 - Prob. 13.4P Ch. 13.7 - Draw the integral trace expected for the NMR...Ch. 13.7 - Prob. 13.6P Ch. 13.8C - Draw the NMR spectra you would expect for the...Ch. 13.8D - Draw the NMR spectra you expect for the following...Ch. 13.8D - a. Assign protons to the peaks in the NMR spectrum...Ch. 13.8D - Prob. 13.10P

Solution Summary: The author explains how the 13C NMR spectrum, including the DEPT technique, would allow distinguishing among the given isomers.

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Chapter 13 Solutions