An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Question
Chapter 1.2, Problem 17P
(a)
To determine
The second term in the virial equation
(b)
To determine
To Explain: The reason for
(c)
To determine
To Calculate: The second and third virial coefficient
(d)
To determine
To Plot: A graph of the Van der Waals prediction for
To calculate: The value of a and b from the above plot.
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Chapter 1 Solutions
An Introduction to Thermal Physics
Ch. 1.1 - Prob. 1PCh. 1.1 - The Rankine temperature scale (abbreviatedR) uses...Ch. 1.1 - Prob. 3PCh. 1.1 - Does it ever make sense to say that one object is...Ch. 1.1 - Prob. 5PCh. 1.1 - Give an example to illustrate why you cannot...Ch. 1.1 - Prob. 7PCh. 1.1 - For a solid, we also define the linear thermal...Ch. 1.2 - What is the volume of one mole of air, at room...Ch. 1.2 - Energy in Thermal Physics Estimate the number of...
Ch. 1.2 - Rooms A and B are the same size, and are connected...Ch. 1.2 - Calculate the average volume per molecule for an...Ch. 1.2 - A mole is approximately the number of protons in a...Ch. 1.2 - Calculate the mass of a mole of dry air, which is...Ch. 1.2 - Estimate the average temperature of the air inside...Ch. 1.2 - Prob. 16PCh. 1.2 - Prob. 17PCh. 1.2 - Prob. 18PCh. 1.2 - Suppose you have a gas containing hydrogen...Ch. 1.2 - Prob. 20PCh. 1.2 - During a hailstorm, hailstones with an average...Ch. 1.2 - Prob. 22PCh. 1.3 - Calculate the total thermal energy in a liter of...Ch. 1.3 - Calculate the total thermal energy in a gram of...Ch. 1.3 - List all the degrees of freedom, or as many as you...Ch. 1.4 - A battery is connected in series to a resistor,...Ch. 1.4 - Give an example of a process in which no heat is...Ch. 1.4 - Estimate how long it should take to bring a cup of...Ch. 1.4 - A cup containing 200 g of water is sitting on your...Ch. 1.4 - Put a few spoonfuls of water into a bottle with a...Ch. 1.5 - Imagine some helium in cylinder with an initial...Ch. 1.5 - Prob. 32PCh. 1.5 - An ideal gas is made to undergo the cyclic process...Ch. 1.5 - An ideal diatomic gas, in a cylinder with a...Ch. 1.5 - Prob. 35PCh. 1.5 - In the course of pumping up a bicycle tire, a...Ch. 1.5 - Prob. 37PCh. 1.5 - Two identical bubbles of gas form at the bottom of...Ch. 1.5 - By applying Newtons laws to the oscillations of a...Ch. 1.5 - In problem 1.16 you calculated the pressure of...Ch. 1.6 - To measure the heat capacity of an object, all you...Ch. 1.6 - The specific heat capacity of Albertsons Rotini...Ch. 1.6 - Calculate the heat capacity of liquid water per...Ch. 1.6 - Prob. 44PCh. 1.6 - Prob. 45PCh. 1.6 - Measured heat capacities of solids and liquids are...Ch. 1.6 - Your 200-g cup of tea is boiling-hot. About how...Ch. 1.6 - When spring finally arrives in the mountains, the...Ch. 1.6 - Prob. 49PCh. 1.6 - Consider the combustion of one mole of methane...Ch. 1.6 - Use the data at the back of this book to determine...Ch. 1.6 - The enthalpy of combustion of a gallon (3.8...Ch. 1.6 - Look up the enthalpy of formation of atomic...Ch. 1.6 - Prob. 54PCh. 1.6 - Heat capacities are normally positive, but there...Ch. 1.7 - Calculate the rate of heat conduction through a...Ch. 1.7 - Home owners and builders discuss thermal...Ch. 1.7 - According to a standard reference table, the R...Ch. 1.7 - Make a rough estimate of the total rate or...Ch. 1.7 - A frying pan is quickly heated on the stovetop to...Ch. 1.7 - Geologists measure conductive heat flow out of the...Ch. 1.7 - Consider a uniform rod of material whose...Ch. 1.7 - Prob. 63PCh. 1.7 - Make a rough estimate of the thermal conductivity...Ch. 1.7 - Prob. 65PCh. 1.7 - In analogy with the thermal conductivity, derive...Ch. 1.7 - Make a rough estimate of how far food coloring (or...Ch. 1.7 - Prob. 68PCh. 1.7 - Imagine a narrow pipe, filled with fluid, in which...Ch. 1.7 - Prob. 70P
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- Problem 6: There are lots of examples of ideal gases in the universe, and they exist in many different conditions. In this problem we will examine what the temperature of these various phenomena are. Part (a) Give an expression for the temperature of an ideal gas in terms of pressure P, particle density per unit volume ρ, and fundamental constants. T = P/( ρ kB ) Part (b) Near the surface of Venus, its atmosphere has a pressure fv= 96 times the pressure of Earth's atmosphere, and a particle density of around ρv = 0.92 × 1027 m-3. What is the temperature of Venus' atmosphere (in C) near the surface? Part (c) The Orion nebula is one of the brightest diffuse nebulae in the sky (look for it in the winter, just below the three bright stars in Orion's belt). It is a very complicated mess of gas, dust, young star systems, and brown dwarfs, but let's estimate its temperature if we assume it is a uniform ideal gas. Assume it is a sphere of radius r = 5.8 × 1015 m (around 6 light years)…arrow_forwardHow many molecules are in a typical object, such as gas in a tire or water in a drink? We can use the ideal gas law to give us an idea of how large N typically is.Calculate the number of molecules in a cubic meter of gas at standard temperature and pressure (STP), which is defined to be 0ºC and atmospheric pressure.arrow_forwardThe volume V of an ideal gas varies directly with the temperature T and inversely with the pressure P. If a cylinder of 50 liters contains oxygen at a temperature of 200 K and a pressure of 5 atmospheres, what would the gas pressure be if the volume was changed to 30 liters and the temperature raised to 240 K?arrow_forward
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- What is the value of the compressibility factor, Z. when the volume of 1 mol of a real gas is smaller than that of 1 mol of an ideal gas at constant pressure and temperature? 7 < 1 Z = 1 Z>1 Z cannot be determinedarrow_forwardConsider the ideal gas H2 at T = 293 K. Use a numerical integration program on a computer to find the fraction of molecules with speeds in the following ranges: (a) 0 to 10 m/s, (b) 0 to 100 m/s, (c) 0 to 1000 m/s, (d) 1000 m/s to 2000 m/s, (e) 2000 m/s to 5000 m/s, and (f) 0 to 5000 m/s.arrow_forwardA)An ideal gas is confined to a container at a temperature of 330 K.What is the average kinetic energy of an atom of the gas? (Express your answer to two significant figures.) B)2.00 mol of the helium is confined to a 2.00-L container at a pressure of 11.0 atm. The atomic mass of helium is 4.00 u, and the conversion between u and kg is 1 u = 1.661 ××10−27 kg.Calculate vrmsvrms. (Express your answer to three significant figures.) C)A gold (coefficient of linear expansion α=14×10−6K−1α=14×10−6K−1 ) pin is exactly 4.00 cm long when its temperature is 180∘∘C. Find the decrease in long of the pin when it cools to 28.0∘∘C? (Express your answer to two significant figures.)arrow_forward
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