(a)
Interpretation:
The most important type of solute-solvent interaction of acetone in water has to be given.
Concept Introduction:
Intermolecular forces: Intermolecular forces are electrostatic in nature and include van der Waals forces and hydrogen bonds. Molecules in liquids are held to other molecules by intermolecular interactions, which are weaker than the intramolecular interactions that hold the atoms together within molecules and polyatomic ions. The three major types of intermolecular interactions are,
- Dipole-dipole interactions
- London dispersion forces
- Hydrogen bonds
(b)
Interpretation:
The most important type of solute-solvent interaction of Iodine bromide in chloroform has to be given.
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
The most important type of solute-solvent interaction of calcium chloride in water has to be given.
Concept Introduction:
Refer to part (a).
(d)
Interpretation:
The most important type of solute-solvent interaction of krypton in methanol has to be given.
Concept Introduction:
Refer to part (a).
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Chemistry: Principles and Practice
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-112 List the following aqueous solutions in order of increasing boiling point: 0.060 M glucose (C6H12O6), 0.025 M LiBr, and 0.025 M Zn(NO3)2.Assume complete dissociation of any salts.arrow_forward6-67 Calculate the freezing points of solutions made by dissolving 1.00 mole of each of the following ionic solutes in 1000. g of H2O. (a) NaCI (b) MgCI2 (c) (NH4)2CO3 (d) AI(HCO3)3arrow_forward
- A solution is made by dissolving 0.455 g of PbBr2 in 100 g of H2O at 50C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedarrow_forward6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin (C3H8O3) 0.025 M NaBr, and 0.015 M AI(NO3)3 Assume complete dissociation of any salts.arrow_forward
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