Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 12, Problem 12.28SP
Interpretation Introduction

Interpretation: The explanation of how the IR spectrum of the product differs from that of the reactant; and the approximate frequencies for distinctive peaks in the IR spectrum of the reactant and also of the product are to be given.

Concept introduction: An IR spectrum is a graph for the energy absorbed by a molecule as a function of the frequency or wavelength of light. Alkanes, alkenes and alkynes have characteristic CH stretching frequencies. Isolated alkenes have a value of  16401680cm1 , and conjugated alkenes have 16201640cm1 frequencies.

To determine: The difference in the product and the reactant in the IR spectrum; and the approximate frequencies for distinctive peaks in the IR spectrum of the reactant and also of the product.

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A student has acquired an IR spectra of an unknown six-carbon molecule and has determined that it is either 2-hexyne, 1- hexyne, or 1-hexene. How can the student use their knowledge of IR spectroscopy to determine the identity of the molecule? In your answer, clearly specify what regions of the IR spectrum the student should look at and what bonds are responsible for the absorption bands you indicate.
Determine the structure for the molecule that most likely produced these spectra.
A common lab experiment is the dehydration of cyclohexanol to cyclohexene. Explain how you could tell from the IR spectrum whether your product was pure cyclohexene, pure cyclohexanol or a mixture of both. Give approximate frequencies for distinctive peaks.
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IR Spectroscopy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=_TmevMf-Zgs;License: Standard YouTube License, CC-BY