What is the experimental yield (grams and percentage)Experiment: Oxidation of -Chlorotoluene to o-Chlorobenzoic acidmaterials useddissolved 3.35 g of KMnO41.20 mL of 2-chlorotoluene was added to the mixture3.0 mL of concentrated hydrochloric acid (pH~2)10 mL of toluene-The crystals were isolated by vacuum filtration-Product Characterization1.15 g of the crude product0.93 g of the final productM.p. (final): 139-141 oC In the experiment, potassium permanganate is used to oxidize 2-chlorotoluene (o-chlorotoluene)to 2-chlorobenzoic acid (o-chlorobenzoic acid). Permanganate solutions are less hazardous thanthose containing chromium compounds, which are often carcinogenic..CH3СООН1. KMnO4, H,О, д2. HСІ, Н,0`CI`ClThe yield of the reaction observed in the literature (Clarke, H. T.; Taylor, E. R. Org. Synth. 1930,10, 20) is 76-78 % before recrystallization and 65-67 % after recrystallization.

Here the reactant is 2-chlorotoluene and the product is 2-chlorobenzoic acid. In the balanced…

What is the experimental yield (grams and percentage) Experiment: Oxidation of -Chlorotoluene to o-Chlorobenzoic acid materials used dissolved 3.35 g of KMnO4 1.20 mL of 2-chlorotoluene was added to the mixture 3.0 mL of concentrated hydrochloric acid (pH~2) 10 mL of toluene -The crystals were isolated by vacuum filtration- Product Characterization 1.15 g of the crude product 0.93 g of the final product M.p. (final): 139-141 oC

What is the experimental yield (grams and percentage) Experiment: Oxidation of -Chlorotoluene to o-Chlorobenzoic acid materials used dissolved 3.35 g of KMnO4 1.20 mL of 2-chlorotoluene was added to the mixture 3.0 mL of concentrated hydrochloric acid (pH~2) 10 mL of toluene -The crystals were isolated by vacuum filtration- Product Characterization 1.15 g of the crude product 0.93 g of the final product M.p. (final): 139-141 oC

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter18: Radical Initiated Chlorination Of 1-chlorobutane

Section: Chapter Questions

Problem 1Q

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