Predict the starting alkyl chloride that would produce the product shown in the SN1 reaction. Assume no rearrangements. Stereochemistry is not considered. 1 1 I 1 Drawing CH3CH2OH I
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- c. Snl reactions dominate under polar protic solvents. Increasing the polarity of the solvent will increase the rate of the reaction because the polar solvent will stabilize the dispersed charges on the transition state more than it will stabilize the neutral reactant. Label areas of ô* and & on the molecules of the transition state of the SN1 reaction below: Me Me Ме Me Me H20 Br -Br OH + НО \'H Et Et RDS Et H Et Et transition state not isolable carbocation intermediate not isolableMy Home OWLV2 | Online teaching and lear X G D /ilrn/takeAssignment/takeCovalentActivity.do?locator=assignment-take IReviaw Toples Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below. You do not have to consider stereochemistry. Draw the enolate ion in its carbanion form. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right comer. Separate multiple reactants using the + sign from the drop-down menu. aste [F ChemDoode Submit Anewer Retry Entro Group 8 more group attempts remainingQ10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. a) Br, CH3 MeOH H3C b) Br NaOH 1 DMF* H3C *N,N-dimethylformamide
- Q12. (1-bromoethyl)benzene 1 udergoes an elimination following an E1 mechanism. Fill in the following synthetic scheme by drawing the structure of intermediate 2 and product 3. The chemical formula of product 3 is provided as guidance. CH; RDS Br C3Hg E1 2 3(d) With reference to the following reaction scheme: Me tBu 13 Reagent(s)? Me!!!. OH E noitesu cheq lo 19van A tBu 146 jqmolts nA (6) lobis boaaono gniau bauogmos prins bns to ouxims ni besteni batles M bon Jelsistum woler (1) Draw cyclohexanone 13 in the lowest energy chair conformation. (ii) Suggest an appropriate reagent to achieve this stereoselective reduction of cyclohexanone 13 to cyclohexanol 14 and explain your choice of reagent (curved arrow mechanisms are not required).One of the steps in the mechanism of the above reaction as shown below. Draw the structure of all the products of this reaction. com/mm/takeAssignCourt Rotivity.do?locator assignment-take 1 pt ment Eto O Eto O 3. NaOH, H₂O, heat 4. HCI, H₂O, heat One of the steps in the mechanism of the above reaction is shown below. Draw the structure of all of the products of this reaction. O OEt O 1. Eto Na 2 Å OH You do not have to consider stereochemistry. • Draw enolate anions in their carbanion form. . You should include all products. Ôno P Ć [References) . Include counter-ions, e.g., Na, I, in your submission, but draw them in their own separate sketcher. . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. . Separate multiple products using the + sign from the drop-down menu. ///-000- IF Previous Email Instructor
- H :O: 819 -CI: :CI: This is an E2 anti elimination. b Draw the organic product of the mechanism step above. Draw POCI3 and its derivatives with a P=O double bond. • You do not have to consider stereochemistry. Ignore alkene stereochemistry. • Do not include counter-ions, e.g., Na+, I, in your answer. Sn [F Correct ChemDoodle"biackboard.gwu.edu/webapPps/assessment/feview/review.jsprattempld Select the major product of the reaction below. 1) TIPSCI, Et3N 2) Na 3) 03, then CH3SCH3 4) CH3CH2LI, then H30* 5) Bu4N* F', H2O CI Selected Answer: Он HO Answers: он он он OH OH OH он Select the major product of the reaction below. The answer is there, but please explain step by step.5. Provide a base to prepare the following major products for each of the following E2 reactions. Explain. Chemistr S Br b) @ OT “Chérsistry SE Chemistry Skips
- Q10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. а) Br CH3 MeOH H3C b) Br NaOH DMF* H3C *N,N-dimethylformamideDraw the major organic product of the reaction shown below. HO NazCr207 H2SO4, H20 H3C CH3 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste ChemDoodleP CHE 124 ORGANIC CHEMISTRY TUT2 2020 (Prote on Failed) Mailings Review View n and might be unsafe. Click for more details. Enable Editing 2. What are the major products obtained from the following reactions? Indicate the geometry (cis/trans). HBr, CH,COOH 近 91 81 61 L. 5. 8. 6.