Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shown.

Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shown.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

Make an electron-flow-mechanism for this synthetic scheme. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shown.( benzene to napthalene) with label

 

6. Haworth Synthesis Friedel Crafts FIRST Clemensen acylation Anhydrous AICI, A reduction CH2 Zn(Hg), conc. HCI CH. Wolff-Kishner CH2 +soci, CH2 -so, -HCit Reduction NH,-NH, & KOH in ethane-1,2-diol 4-oxo-4-phenyl solvent benzene 4-phenyl butanoic acid 4-phenyl butanoyl chloride (r-phenyl butyryl chloride) succinic anhydride butanoic acid (B-benzoyl (r-phenyl butyric acid) propionic acid) Dehydration / Cyclization Conc H,SO, PPA / P,0;/-H,0 HF I Conc H,PO, -HCit Friedel Crafts intramolecular acylation Anhydrous AICI, I SnC, A SECOND Clemensen reduction Dehydrogenation / Oxidation/ Aromatization Palladised Charcoal (Pd-C)/ Selenium A -2H, Zn(Hg).HCI Wolf-Kishner Reduction NH, NH, & KOH in ethane-1,2-diol naphthalene 1,2,3,4-tetrahydro naphthalene (tetralin) 3,4-dihydro naphthalen-1(2H)-one (a-tetralone) solvent
Transcribed Image Text:6. Haworth Synthesis Friedel Crafts FIRST Clemensen acylation Anhydrous AICI, A reduction CH2 Zn(Hg), conc. HCI CH. Wolff-Kishner CH2 +soci, CH2 -so, -HCit Reduction NH,-NH, & KOH in ethane-1,2-diol 4-oxo-4-phenyl solvent benzene 4-phenyl butanoic acid 4-phenyl butanoyl chloride (r-phenyl butyryl chloride) succinic anhydride butanoic acid (B-benzoyl (r-phenyl butyric acid) propionic acid) Dehydration / Cyclization Conc H,SO, PPA / P,0;/-H,0 HF I Conc H,PO, -HCit Friedel Crafts intramolecular acylation Anhydrous AICI, I SnC, A SECOND Clemensen reduction Dehydrogenation / Oxidation/ Aromatization Palladised Charcoal (Pd-C)/ Selenium A -2H, Zn(Hg).HCI Wolf-Kishner Reduction NH, NH, & KOH in ethane-1,2-diol naphthalene 1,2,3,4-tetrahydro naphthalene (tetralin) 3,4-dihydro naphthalen-1(2H)-one (a-tetralone) solvent
Expert Solution
steps

Step by step

Solved in 6 steps with 5 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS