CH,C-H H3C CH * CH3 II III a. Underline the most acidic hydrogens in each of the molecules. b. Rank the molecules above in order of increasing acidity (least acidic to most acidic). а. III, II, I

Organic Chemistry
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ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.46AP
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4.
Consider the structures below to answer the following question(s).
CH,C-H
OH
CH
"CH3
I
II
III
a. Underline the most acidic hydrogens in each of the molecules.
b. Rank the molecules above in order of increasing acidity (least acidic to most acidic).
III, II, I
а.
b. II, III, I
I, II, II
с.
d. II, I, II
5. Nitroethane [CH3CH2NO2, pka = 8.6] is a much stronger acid than ethane [CH3CH3, pka = 60]. Explain.
Transcribed Image Text:4. Consider the structures below to answer the following question(s). CH,C-H OH CH "CH3 I II III a. Underline the most acidic hydrogens in each of the molecules. b. Rank the molecules above in order of increasing acidity (least acidic to most acidic). III, II, I а. b. II, III, I I, II, II с. d. II, I, II 5. Nitroethane [CH3CH2NO2, pka = 8.6] is a much stronger acid than ethane [CH3CH3, pka = 60]. Explain.
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