Please help and explain 2. For each pair of compounds, circle the strongest acid:NO2HO-HO-a.HO.vs.HO.b.VS.H.H.tHO.C.d.H3Nvs.H3N+

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Answered: 2. For each pair of compounds, circle…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter4: Polar Bonds, Polar Reactions

Section: Chapter Questions

Problem 22CTQ

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Use Table 13-2 to order the following from the strongest to the weakest acid. HClO2,H2O,NH4+,HClO4
. For each pair of concentrations, tell which represents the more basic solution. a. [H+]=2.02107Mor[OH-]=5.05105M b. [H+]=1.79105Mor[OH-]=4.21106M c. [H+]=1.251012Mor[OH-]=6.51103M
Gastric juice, the digestive ?uid produced in the stomach, contains hydrochloric acid, HCl, Milk of Magnesia, a suspension of solid Mg(OH)2 in an aqueous medium, is sometimes used to neutralize-excess stomach acid. Write a complete balanced equation for the neutralization reaction, and identify the conjugate acid—base pairs.
Consider two separate solutions: one containing a weak acid. HA, and one containing HCl. Assume that you start with 10 molecules of each. a. Draw a molecular-level picture of what each solution looks like. b. Arrange the following from strongest to weakest base: Cl- H2O. A- . Explain.
Salicylic acid, HOC6H4CO2H, and its derivatives have been used as pain relievers for a long time. Salicylic acid occurs in small amounts in the leaves, bark, and roots of some vegetation (most notably historically in the bark of the willow tree). Extracts of these plants have been used as medications for centuries. The acid was first isolated in the laboratory in 1838. (a) Bath functional groups of salicylic acid ionize in water, with Ka=1.0103 for the—CO2H group and 4.201013 for the -OH group. What is the pH of a saturated solution of the acid (solubility = 1.8 g/L).. (b) Aspirin was discovered as a result of efforts to produce a derivative of salicylic acid that would not be irritating to the stomach lining. Aspirin is acetylsalicylic acid, CH3CO2C6H4CO2H. The -CO2H functional group is still present, but its acidity is reduced, Ka=3.0104. What is the pH of a solution of aspirin with the same concentration as a saturated solution of salicylic acid (See Part a). (c) Under some conditions, aspirin reacts with water and forms a solution of salicylic acid and acetic acid: CH3CO2C6H4CO2H(aq)+H2O(l)HOC6H4CO2H(aq)+CH3CO2H(aq) i. Which of the acids, salicylic acid or acetic acid, produces more hydronium ions in such a solution? ii. What are the concentrations of molecules and ions in a solution produced by the hydrolysis of 0.50 g of aspirin dissolved in enough water to give 75 mL of solution?
For the previous four questions, label each molecule that appears in the question or your answer asstrong acid, strong base, weak acid, or weak base.
The following reactions illustrate Brnsted acid-base behavior. Complete each equation. a.HI(aq)+?H3O+(aq)+I(aq) b.NH3(l)+?NH4++NH2 c.H2C2O4(aq)+H2O(l)?+HC2O4(aq) d.H2N2O2(aq)+H2O(l)H3O+(aq)+? e.?+H2O(l)H3O+(aq)+CO32(aq)
35. For each pair of concentrations, tell which represents the more acidic solution. a. [H+]=1.2103Mor[H+]=4.5104M b. [H+]=2.6106Mor[H+]=4.3108M c. [H+]=0.000010Mor[H+]=0.0000010
Use Table 14.3 to help order the following acids from strongest to weakest HNO3,H2O,NH4+,C5H5NH+

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2. For each pair of compounds, circle the strongest acid: NO2 a. HO, vs. ОН b. H-H C. vs. d.