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- Boron is an anomaly in Group 13 in that it forms covalent compounds rather than ionic Suggest an explanation for this divergent behavior.
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- (a) Which poisonous gas is evolved when white phosphorus is heated with Cone. NaOH solution? Write the chemical equation. (b) Write the formula of first noble gas compound prepared by N. Bartlett. What inspired N. Bartlett to prepare this compound? (c) Fluorine is a stronger oxidising agent than chlorine. Why? (d)Write one use of chlorine gas.(b) Is boron a metal or a non-metal? Give reasons for your answer. (c) Why is aluminium a useful structural material even though it reacts readilywith water and oxygen? (d) What is the usual valence shown by elements of Group 13 in compounds?Nitrogen exists as a diatomic molecule with a triple bond between the twoatoms, whereas the heavier elements of the group do not exist as E2at room temperature. Assign a reason.
- (a) (i) (ii) (iii) With the aid of a simple schematic, explain what covalent bonding is and how it is formed. What are the differences between a covalent bond and an ionic bond? Which type of bond is found in crystalline silicon? At room temperature do you expect an ionic crystal to be a good electrical conductor or a good electrical insulator? Explain why.Ionic hydrides are primarily compounds of hydrogen and nonmetals, in which the bonds are evidently electron pairs shared by atoms of comparable electronegativities.(a) What are the common oxidation states of the halogens?(b) Give an explanation based on electron configuration for the range and values of the oxidation states of chlorine.(c) Why is fluorine an exception to the pattern of oxidation states found for the other group members?
- Compounds such as NaBH4, Al(BH4)3, and LiAlH4 are complex hydrides used as reducing agents in many syntheses. (a) Give the oxidation state of each element in these compounds. (b) Write a Lewis structure for the polyatomic anion in NaBH4, and predict its shape.The oxygen and nitrogen families have some obvious sim-ilarities and differences.(a) State two general physical similarities between Group5A(15) and 6A(16) elements. (b) State two general chemical similarities between Group5A(15) and 6A(16) elements.(c) State two chemical similarities between P and S.(d) State two physical similarities between N and O.(e) State two chemical differences between N and O.Nitrogen is found in nature as N2(g). Would you expect phosphorus to be found innature as P2(g)? Explain.
- Out of white phosphorus and red phosphorus, which one is more reactive and why?How many electrons does a halogen atom need to complete its octet? Give examples of the ways a Cl atom can do so.Compounds such as NaBH₄, Al(BH₄)₃, and LiAlH₄ arecomplex hydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH₄,and predict its shape.
