Assuming that neither standard enthalpy changes of formations (∆Hof)  nor standard molar entropies (So) depend upon temperature, estimate using the Table of Thermodynamic Data : (a) the standard Gibbs free energy change for the reaction that forms rhombic sulfur at 600 K, and (b) the temperature (in oC) at which reaction will stop  formation of products:   2H2S(g) + SO2(g) → 3S(rhombic, s) + 2H2O(g)  Round off your answers to the nearest integer. Report the temperature in oC. and enter them with correct units:  (a)∆Gorxn = (b) T =

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Assuming that neither standard enthalpy changes of formations (∆Hof)  nor standard molar entropies (So) depend upon temperature, estimate using the Table of Thermodynamic Data : (a) the standard Gibbs free energy change for the reaction that forms rhombic sulfur at 600 K, and (b) the temperature (in oC) at which reaction will stop  formation of products:  

2H2S(g) + SO2(g) 3S(rhombic, s) + 2H2O(g) 

Round off your answers to the nearest integer. Report the temperature in oC. and enter them with correct units: 

(a)∆Gorxn =

(b) T =

a reader.yuzu.com/n/books/9781260162370/ct6/82/4/8/4/4/184/2/ze0:0
Fe,O,(s)
-822.2
-741.0
90.0
Fe(OH),(s)
-568.19
-483.55
79-5
Fe(OH),(s)
-824.25
-696.5
106.7
H(g)
218.2
203.2
114.6
131.0
H,G)
H*(aq)
OH (aq)
-229.94
-157-30
-10.5
HO()
-285.8
-237.2
69.9
H,O(g)
-241.8
-228.6
188.7
H,0,()
-187.6
-118.1
Hg(D
77-4
Hg"(aq)
-164-38
-32.2
171.1
HgO(s)
-90.7
-58.5
72.0
HBCL,(s)
-230.1
-178.6
146.0
Hg Cl,(s)
-264.9
-210.66
196.2
HgS(s)
-58.16
-48.8
77.8
HESO,(s)
-704.17
-595
140
Hg, SO,(s)
-623.92
200.75
-741.99
L(s)
116.7
中 Aa
A-4
Transcribed Image Text:a reader.yuzu.com/n/books/9781260162370/ct6/82/4/8/4/4/184/2/ze0:0 Fe,O,(s) -822.2 -741.0 90.0 Fe(OH),(s) -568.19 -483.55 79-5 Fe(OH),(s) -824.25 -696.5 106.7 H(g) 218.2 203.2 114.6 131.0 H,G) H*(aq) OH (aq) -229.94 -157-30 -10.5 HO() -285.8 -237.2 69.9 H,O(g) -241.8 -228.6 188.7 H,0,() -187.6 -118.1 Hg(D 77-4 Hg"(aq) -164-38 -32.2 171.1 HgO(s) -90.7 -58.5 72.0 HBCL,(s) -230.1 -178.6 146.0 Hg Cl,(s) -264.9 -210.66 196.2 HgS(s) -58.16 -48.8 77.8 HESO,(s) -704.17 -595 140 Hg, SO,(s) -623.92 200.75 -741.99 L(s) 116.7 中 Aa A-4
reader yunu.com/mbooks/9781
Thermodynamic Data at 1 atm and 25°C*
Inorganic Substances
S J/K - mol)
AH (K/mol
AG (kJ/mol)
Substance
42.7
Ag(s)
73-9
771
105.9
Ag (ag)
AgCls)
AgBr(s)
-109.7
96.1
-127.0
-95-9
107.1
-99.5
-624
-66.3
114.2
Aglis)
-32.2
140.9
-123.1
ARNO,(s)
28.3
Al(s)
-4812
-313-38
AP (ag)
-524-7
-630.0
109-3
AICI,()
-705.6
Al,0,()
-1669.8
-15764
50.99
As(s)
35-15
Aso ag
-870.3
-635.97
-144-77
68.9
222 8
AsH,(g)
HASO,6)
171.5
-900.4
-766
184
Auts)
47-7
口
8 Aa 40
A-2
Transcribed Image Text:reader yunu.com/mbooks/9781 Thermodynamic Data at 1 atm and 25°C* Inorganic Substances S J/K - mol) AH (K/mol AG (kJ/mol) Substance 42.7 Ag(s) 73-9 771 105.9 Ag (ag) AgCls) AgBr(s) -109.7 96.1 -127.0 -95-9 107.1 -99.5 -624 -66.3 114.2 Aglis) -32.2 140.9 -123.1 ARNO,(s) 28.3 Al(s) -4812 -313-38 AP (ag) -524-7 -630.0 109-3 AICI,() -705.6 Al,0,() -1669.8 -15764 50.99 As(s) 35-15 Aso ag -870.3 -635.97 -144-77 68.9 222 8 AsH,(g) HASO,6) 171.5 -900.4 -766 184 Auts) 47-7 口 8 Aa 40 A-2
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