An orange juice is thermally processed for determining ascorbic acid degradation kinetics. After different temperature experiments, the following ascorbic acid concentration values were obtained:       Ascorbic Acid (mg/L) Processing Time (second)     0 15 30 60 90 120 Temperature (oC) 75 558.3 546.5 535 526.5 519.6 508.6 85 608.6 595.2 587.4 572.7 557.5 542.3 95 612.6 601.5 588.2 546.1 521.8 509.5     According to the results; Determine ascorbic acid degradation order Derive the equations related to the degradation order (general equation and t1/2) Calculate k-values at the constant processing temperatures Calculate activation energy (Ea) of the degradation reaction Calculate half-life time of ascorbic acid for all processing (For better evaluation, add figures for the addressed questions, if necessary)

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 1.2ACP
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An orange juice is thermally processed for determining ascorbic acid degradation kinetics. After different temperature experiments, the following ascorbic acid concentration values were obtained:

 

 

 

Ascorbic Acid (mg/L)

Processing Time (second)

 

 

0

15

30

60

90

120

Temperature (oC)

75

558.3

546.5

535

526.5

519.6

508.6

85

608.6

595.2

587.4

572.7

557.5

542.3

95

612.6

601.5

588.2

546.1

521.8

509.5

 

 

According to the results;

  1. Determine ascorbic acid degradation order
  2. Derive the equations related to the degradation order (general equation and t1/2)
  3. Calculate k-values at the constant processing temperatures
  4. Calculate activation energy (Ea) of the degradation reaction
  5. Calculate half-life time of ascorbic acid for all processing

(For better evaluation, add figures for the addressed questions, if necessary)

                                                                                                                             

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