An aqueous solution containing 5.13 g of an optically-pure compound was diluted to 5.00 x 102 mL with water and placed in a 15.0 cm long polarimeter tube. The measured rotation was -2.55° at 25° C. Calculate the specific rotation of the compound. [a] =
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- An aqueous solution containing 7.57 g of an optically-pure compound was diluted to 2.00×102 mL with water and placed in a 10.0 cm long polarimeter tube. The measured rotation was −4.11° at 25° C. Calculate the specific rotation of the compound.If a solution of a compound (50.0 g/100 mL of solution) has a measured rotation of +15° in a 2 dm tube, the specific rotation is: * +20 +35 O+15 O +8 O O O O5. A solution containing 2.0g of compound dissolved in 50mL of solvent generated an observed rotation of plane-polarized light (A = 589.6nm) of 20° in a polarimeter tube 300mm long at a temperature of 25°C. What is the specific rotation of the compound?
- A solution of 2.0 g of (+)-glyceraldehyde, HOCH2CHOHCHO, in 10.0 mL of water was placed in a 100-mm cell. Using the sodium D line, a rotation of +1.74° was found at 25 °C. Determine the specific rotation of (+)@glyceraldehyde.In his classic studies of stereochemistry and optical activity in organic compounds, Pasteur measured the optical activity of many solutions. For the naturally occurring enantiomer of tartaric acid, [α]D20 = +12.4o (c = 20, H2O). What can be concluded about the ratio of tartaric acid enantiomers present in the solution if the observed rotation α = 0o?50 uL of an aqueous sample of double-stranded DNA is dissolved in 950 uL of water. This diluted solution has a maximal absorbance of 0.326 at 260 nm. What is the concentration of the original (more concentrated) DNA sample, expressed in ug/uL?
- Guanosine has a maximum absorbance of 275 nm. ϵ275= 8400M−1cm−1 and the path length is 1 cm. Using a spectrophotometer, you find the that A275=0.70. What is the concentration of guanosine?Calculate the specific rotation of a solution of a compound (30.0 g/100 mL of solution) that has a measured rotation of +25.25º in a 2.00 dm tube.The specific rotation of (R)-2-butanol is 13.5° counterclockwise. A sample containing (R)-2-butanol was made by dissolving 1.75 g into a solution with a total volume of 3.55 mL. The light source was a sodium D line and the temperature was 25° C. The length of the sample tube was 12.5 cm. What was the observed rotation of the sample? "Use three significant figures for your answer and the correct sign.
- Which is the more reliable technique for identifying an unknown compound and why? IR spectrum Melting point Thin-layer chromostography (TLC)Ibuprofen, 2-[4-(2- methylpropyl)phenyl]propanoic acid, is a medication used to reduce pain, fever, or inflammation. It is slightly soluble in pure water but well soluble in alcohols. From the formula of this molecule, is it possible to determine this molecule spectrophotometrically in solution without adding any reagents? Explain why yes or why not. CH3 CH3 но H3CA 0.1 g amine-containing compound is dissolved in water then diluted to 100 mL. To get the concentration of amine in this compound, you subject it to spectroscopic analysis. So, you get 1 mL of the previously diluted sample then dilute it again to 250 mL for measurement. Then, you fill 3/4 of a 1-cm cuvette with this diluted sample then you run an analysis using an AAS. The recorded absorbance is 0.545 at 410 nm. Solve for the molecular weight of the compound. The molar absorptivity is 1.23 x 104 cm-1 mol-1 L.