A titration experiment required 12.50 ml of standard hydrochloric acid solution to reach the phenolphthalein endpoint. A few drops of methyl orange were added into the analyte, and it consumed 23.60 mL more of the standard acid solution. Which of the following is TRUE about the analysis? O The analyte contains only sodium carbonate solution. O The analyte contains sodium hydroxide and sodium bicarbonate solution. O The analyte contains both sodium carbonate and sodium bicarbonate solution. O The analyte contains sodium hydroxide only O The analyte contains only sodium bicarbonate solution.

A titration experiment required 12.50 ml of standard hydrochloric acid solution to reach the phenolphthalein endpoint. A few drops of methyl orange were added into the analyte, and it consumed 23.60 mL more of the standard acid solution. Which of the following is TRUE about the analysis? O The analyte contains only sodium carbonate solution. O The analyte contains sodium hydroxide and sodium bicarbonate solution. O The analyte contains both sodium carbonate and sodium bicarbonate solution. O The analyte contains sodium hydroxide only O The analyte contains only sodium bicarbonate solution.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter20: Applications Of Oxidation/reduction Titrations

Section: Chapter Questions

Problem 20.6QAP

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A 50-mL solution of 0.5005 N standard NaOH was added to a 0.9250-g sample of Aspirin and was boiled for 10 minutes. After cooling a full pipet of phenolphthalein was added to the solution before it was titrated with 24.7 mL of 0.5015 N standard HCl solution until the disappearance of the pink color. The same procedure was carried using a blank which consumed 4.6 mL of the same standard acid. Calculate for the %Aspirin in the sample. Atom weights: C =12, H =1, O =16.
An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 311 mL of the standard acid. What is/are the component/s of the sample? O Cannot be determined O NAHCO3 only O NAOH and Na,CO3 O NazCO3 only O NAHCO, and Na2CO3
An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 mL of the standard acid. What is/are the component/s of the sample? O NazCO3 only NaHCO3 only O NAHCO3 and Na>CO3 NaOH and NazCO3 O Cannot be determined
Twenty sodium salicylate tablets labeled 325 mg were dispersed in sufficient water to make 200.0 ml. A 15.0-ml aliquot of the filtrate was titrated to a bromophenol blue end point in the usual way by 29.11 ml of 0.1000 N hydrochloric acid. Calculate the amount of sodium salicylate in each tablet and, from that, the percentage of the labeled amount. Hint: Use the above formula.
A 100 mL sample contains H3PO4 and NaH2PO4. A 10 mL aliquot was taken and methyl orange was added as indicator into the solution. The sample solution was titrated with 3.0 mL of 0.10 M NaOH solution. Another 10 mL aliquot was taken and phenolphthalein was added as indicator into the solution and the sample solution was titrated with 11.0 mL of 0.10 M NaOH solution. Calculate the amounts of H3PO4 and NaH2PO4 in the sample as mg/100 mL. (write all chemical reactions, Na:23, P:31, O:16, H:1 g/mol).
Used 24.38 mL of a 0.1014M NaOH solution to titrate the dilute HCL solution to the endpoint in one trial. The concentration of the dilute HCl solution = 0.09889M and the concentration of the stock HCl=0.9889M. Then was pipetted 25.00 mL of the stock HCl and added antacid tablet and determined the concentration of the antacid-HCl = 0.6279 M. What was the ANC of the antacid tablet (moles of H+ neutralized per tablet)?
An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO2 free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 mL of the standard acid. How many millimoles of the components are there in the original solid sample? O 0.28 mmol Na,CO3 O 1.29 mmol NaOH, 0.97 mmol Na2CO3 O 0.103 mmol NaOH, 0.078 mmol NazCO3 O 1.29 mmol Na2CO3, 0.97 mmol NaHCO3 O Cannot be determined
Suppose that extra volume (more than the actual volume) of 0.2 M NaOH solution was used to reach the end-point in the titration process for the determination of the % purity of aspirin sample (0.5 g). Which of the following is correct? The calculated and the actual percent purity values for the aspirin sample will be the same, since the extra added volume of NaOH solution has no effect on the % purity determination for the aspirin sample. We need to know the actual volume (the real volume that should be used in titration) as well as the used volume of NaOH solution to make a true comparison between the actual and the calculated % purity values for the aspirin sample. The calculated % purity value will be lower than the actual % purity value for the aspirin sample. The calculated % purity value will be higher than the actual % purity value for the aspirin sample.
A chemist received different mixtures for analysis with the statement that they contained NAOH, NaHCO3, Na,CO3 or compatible mixtures of these substances together with inert material. From the data given, identify the respective materials. Sample 4. The sample was titrated with acid until the pink of phenolphthalein disappeared; this process required 39.96 mL. On adding an excess of the acid, boiling and titrating back with NAOH, it was found that the base was equivalent to the excess acid. O A NazCO3, NaHCO3 OB. NaHCO3 O C. Na2CO3 O D. None of these O E. NaOH
A double indicator analysis of a soda ash sample was performed. The student weighed 0.4375 g of the soda ash sample and dissolved it to make 100.0 mL solution. The students then took a 25 mL aliquot of the sample solution, then added 25 mL H2O and performed double indicator titration. The phenolphthalein endpoint required 10.27 mL 0.04027 M HCl titrant. The sample was further titrated using Methyl Orange and took a total of 15.97 mL of the titrant to reach the endpoint. Given that the molar weight of Na2CO3 - 105.99 g/mol, NaHCO3 = 84.007 g/mol, and NaOH - 39.997 g/mol answer the following: a. What are the components of the soda ash sample? (The constituents of the sample came from Na2CO3, NaHCO3, and NaOH). b. What are the moles of each component in the titrated 25 mL aliquot? c. What is the percent composition in (% w/w) of each component in the soda ash sample?
Calculate the percentage CH3COOH in a sample of vinegar from the following data.Sample = 15.00 g, NaOH used = 43.00 ml ; 0.600 N H2SO4 used for back titration =0.250 ml ; 1.00ml NaOH is equivalent to 0.0315 g H2C2O4. 2H2O.
Julius Novachrono added a standard solution to an analyte until the reaction between the analyte and the reagent is judged to be complete. What process did he just do? A) Filtration B) Interlocution Gravitation D) Titration