Answered: 4. Using resonance structures, show how…

4. Using resonance structures, show how the intermediate is stabilized in the reaction of p-chloronitrobenzene with pyrrolidine in the substitution reaction shown: NO, NO 2 H +

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter17: Nucleophilic Substitution Reactions Of Alkyl Halides

Section: Chapter Questions

Problem 3Q

See similar textbooks

Related questions

Q: The Ksp of lead(II) hydroxide, Pb(OH)2, is 1.43 × 10-20. Calculate the molar solubility, s, of this ...

Q: Aldehydes and ketones, both contain a common group called ---. Question 24 options: alcohol gr...

A: Aldehyde and ketone has group C=O .

Q: Determine the relation between the pH values of the two solutions. Select the correct choice below a...

A: pH = -log [H+]

Q: The concentration H* of a substance is 1010. Calculate the pH value and classify it as an acid or a ...

Q: 6.) Since all the products have the same molecular weight, you can closely approximate the density o...

A: We have find out theoretical yeild in ml.

Q: Calculate the pH of a 6.6 x 103-M solution of H3SO4 (K, = 1.2 x 10-2). %3D pH = Submit Answer Try An...

A: Sulphuric acid is a strong acid.It completely dissociated into ions in aqueous solution. pH of a str...

Q: 1) Write the balanced equilibrium reaction for the dissolution of barium nitrate in a saturated solu...

A: 1. Sol :- Given compound is : Ba(NO3)2 1) Write the balanced equilibrium reaction for the dissolut...

Q: Name the highlighted chemical group in each molecule. Lewis structure name of highlighted group H Н—...

Q: What kind of reaction is 2NaOH + H2SO4 -----> Na2SO4 + 2H2O

A: 2NaOH + H2SO4 -----> Na2SO4 + 2H2O

Q: Describe four colligative properties of solutions.

A: Colligative properties are the properties of a solution that depend on the ratio of the total number...

Q: CH3-CH=CHC=c- C3DCH2 43 2.

A: 1. Select the principle carbon chain 2. Numbering 3. Naming (prefix + word root + suffix)

Q: Decide whether each molecule or polyatomic ion is polar or nonpolar. If the molecule or polyatomic i...

Q: Does a reaction occur when aqueous solutions ofsodium hydroxide and calcium acetate are combined ...

A: We have to predict the net ionic equation.

Q: on 1 of 3 The decomposition of N,O, can be described by the equation 2N,0, (soln) 4 NO, (soln) + O,(...

Q: Calculate the pH after addition of 0.00, 10.00, 20.00, 40.00, 41.00, and 50.00 mL of 0.4000 M NaOH i...

Q: Consider the following chemical reaction: 2H2O(1) → 2H2 (g) + O2(g) What mass of H2 0 is required to...

A: Note : Since you have posted multiple questions, we are entitled to answer the first only. Please re...

Q: A chemist makes 930. mL of barium chloride (BaCl,) working solution by adding distilled water to 200...

A: A chemist makes 930. mL of barium chloride BaCl2 working solution by adding distilled water to 200. ...

Q: 1. Provide a correct name for the following compounds: HO ОН CH3 H3C° ÓH CH3 а) NO 2 b)

Q: The symmetry factor β was determined to be 0.4 for an activation controlled Ag deposition process. A...

Q: Does a reaction occur when aqueous solutions of potassium sulfide and calcium acetate are combined? ...

A: potassium sulfide and calcium acetate are combined to form Calcium sulfide and potassium acetate.

Q: Purification of benzoic acid 1. What is the purpose of washing the crystal in the filter paper with...

A: 1) Answer: Benzoic acid is prepared from toluene industrially. Toluene is react with cl2 gas under ...

Q: 0/5 O ACIDS AND BASES Calculating the pH at equivalence of a titration A chemist titrates 190.0 mL o...

Q: Determine the percent composition of BF3 if a 75.0 sample of BF3 decomposes and produces 63.1 g of f...

Q: A chemist adds 160.0 mL of a 2.8 mol/L sodium chloride (Nacl solution to a reaction flask, Calculate...

A: Volume=160mL Molarity =2.8 mol/L

Q: What does the number in a filter paper's brand represent?

Q: Consider the following reaction: A2(g) + B2(g) → 2 AB(g) AHºrxn = -8.06 kJ mol 1 The equilibrium con...

A: The Arrhenius equation is k = Ae^(-Ea/RT), where A is the frequency or pre-exponential factor.

Q: The mass percent of calcium [Ca, MM = 40.08 g/mol) in calcium carbonate [CaCO3, MM = 100.09 g/mol] i...

A: Mass of Calcium carbonate = 12.0 g

Q: A chemist is performing a chemical reaction under a fume hood. The chemist has a set of beakers, fla...

A: Answer: This question is based on the fundamental understanding of thermodynamics that gives us the ...

Q: Differentiate molality and molarity. Name other ways of describing quantitatively compositions of s...

Q: how to determine which is one is organic layer and aqueous layer? Is the large part always the aqueo...

A: An easy way to find out which layer is on top is to fill the funnel with water. Wherever water goes,...

Q: Is it possible to make an ethanol or ethyl alcohol from papaya?

Q: rite balanced net ionic equations describing each of the following reactions: Precipitation of tin (...

A: Write belanced net ionic equations describing of the following reactions.a) Precipitation of tin (4)...

Q: Above what Fe² + concentration will Fe(OH), precipitate from a buffer solution that has a pH of 9.74...

A: Given: The Ksp of Fe(OH)2 = 4.87 × 10-17 We have to calculate the concentration of Fe2+ above which ...

Q: H3C CI NaBH, CH3 AICI,

A: CH3COCl, AlCl3 ====> Friedel Craft acylation reaction NaBH4 ====> Reduction

Q: СНО CO2H CO2ET

A: To solve this problem first we have to use strong oxidizing agent to convert aldehyde to carboxylic ...

Q: A mixture of ascorbic acid (C6H,06H, Ka = 6.8 x 105) and sodium ascorbate is prepared such that [C6H...

Q: The Ksp of Fe(OH)3(s) is 3x10-39. What concentration of Fe3+ can exist in solution at pH 3.0?

A: Ksp = [ Fe+3] [ OH- ] 3

Q: Consider the following reaction at 117O K. Hy(0) + co,te) H,0g) + coG) af the reaction is started in...

A: Hydrogen reacts with carbon dioxide to form water and carbon monoxide. The equation for the balanced...

Q: please solve

Q: Predict the location where a new substituent will be added when this aromatic compound undergoes an ...

Q: a) Calculate the standard potential for the reaction AgsAsO4+ 3e°2 3Ags) + AsO² b) Give a schematic ...

A: As per the guideline, since you have posted a question with multiple sub-parts, we have solved the...

Q: + 'CI

Q: the contact process, sulfuric acid is manufactured by first oxidizing SO2 to SO3, which is then reac...

Q: Balance the following redox reaction in basic solution. MnO,(s)+Br,(1) MnO,(aq)+Br (aq) Mno,(s) + Br...

Q: An aqueous solution is made by mixing 4.3 mL of 0.40M Co(NO3)2 and 8.7 mL of 12.0 M HCI, and the fol...

Q: HClO4 M. a. Write the balanced reaction which occurs during the titration: Reaction: b. Label the di...

A: PH = - log [H+] Where [H+] = concentration of H+ Note : As per our company guideline we can answer o...

Q: The labels came off four cleaning solution containers found under a k ink. Each of the cleaning solu...

Q: 2. In the titration of 50 ml. of 0.05 M of AGNO; solution with 0.05 M KSCN solution, calculate the m...

Q: Write the formula of the conjugate acid of CH₃CH₂O⁻

A: To solve this problem we have to write the formula of conjugate acid of given ionic compound.

Q: Write the Hamiltonian operator for the LiH molecule. Which of the terms in the Hamiltonian operator ...

Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

4. Using resonance structures, show how the intermediate is stabilized in the reaction of
p-chloronitrobenzene with pyrrolidine in the substitution reaction shown:
NO 2
NO2
H
N.
N
CI
+

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

What is the structural requirement for a substance to react with ammoniacal AgNO3? Why would acetylene react with Tollen's reagent but not cyclohexane or cyclohexene?
When 2-pentene is treated with Cl2 in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages).
What is the major monosubstitution product from the Friedelâ€”Crafts reaction of benzene with 1 -chloro-2-methylpropane in the presence of AlCl3?
Why does the reaction of t-butanol with sulfuric acid gives the elimination product isobutylene whereas the reaction with HCl gives predominantly the substitution product?
X Upon ozonolysis, Compound X produces two compounds: Compound Y and Compound Z. Compound Y can also be prepared from the following synthetic route: PCC 1. R₂BH, THF 1. Mg. Et₂O PCC Compound Y 2. CH₂Cl₂ 2. NaOH, HO CH₂Cl₂ 3. H₂O* From this information, draw the structures of Compounds X, Y, and Z. For Compounds X and Z, different substituents are possible. For grading purposes, just use hydrogens as the substituents. Br مرد →] ►
CH3 Ph3P-CHCH3 H3C H3C Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction. In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an oxaphosphetane. The oxaphosphetane is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene. Ph3P-CHCH3 H3C The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an S 2 reaction, followed by deprotonation of the carbon with a strong base, such as butyllithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene :0: CH3 Com The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the C-C bond is precisely where the C=O bond was in the reactant and no isomers (other than…
An unknown hydrocarbon A with the formula C6H10 reacts with 1 molar equivalent of H2 over a palladium catalyst to give B C6H12 (Rxn 1). Hydrocarbon A also reacts with OsO4 to give the glycol C (Rxn 2). A gives 5-oxohexanal on ozonolysis (Rxn 3). Draw the structures of A, B, and C. Give the reactions.
Write a balanced equation for the oxidation of p-xylene to 1,4-benzenedicarboxylic acid (terephthalic acid) using potassium dichromate in aqueous sulfuric acid. How many milligrams of H2CrO4 are required to oxidize 250 mg of p-xylene to terephthalic acid?
What does alkyl halides gives on heating with dry Ag2O ?
Ph3P-CHCH3 H₂C H3C Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction. In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an oxaphosphetane. The oxaphosphetane is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene. CH3 00 + The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an SN2 reaction, followed by deprotonation of the carbon with a strong base, such as butyllithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene X m CH3 The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the C=C bond is precisely where the C=O bond was in the reactant and no isomers (other than E/Z isomers)…
What organic product would you obtain from reaction of 1-pentanol with CrO3, H2O, H2SO4?
A compound with formula C7H12O is treated with sodium borohydride in methanol to yield 2,2-dimethylcylopentanol. Write a reaction scheme showing the structures of the reactant, the reagents, and the product. Will the product be optically active? Explain.