32. Benzyl chloride is reacted with different nucleophiles (HO, CH:CO0, PhO, CH:O). Arrange them in the decreasing order of reactivity with benzyl chloride. Note: A. CH:O> HO > PhO> CH:C00 B. HO> CH:O> Pho> CH:C00- C. HO-> Pho> CH;O-> CH;CO0- D. CH:COO > CH:O>HO¯> PhO benzyl chloride PhO, phenoxide

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

32 33 34

32. Benzyl chloride is reacted with different nucleophiles (HO-, CH;CO0, PhO, CH30-).
Arrange them in the decreasing order of reactivity with benzyl chloride.
A. CH:O > HO> PhO> CH:COO-
Note:
B. HO-> CH3O- > Pho> CH;CO0-
C. HO> Pho > CH3O-> CH3CO0-
D. CH:COO> CH3O> HO> PhO
benzyl chloride
PhO, phenoxide
Transcribed Image Text:32. Benzyl chloride is reacted with different nucleophiles (HO-, CH;CO0, PhO, CH30-). Arrange them in the decreasing order of reactivity with benzyl chloride. A. CH:O > HO> PhO> CH:COO- Note: B. HO-> CH3O- > Pho> CH;CO0- C. HO> Pho > CH3O-> CH3CO0- D. CH:COO> CH3O> HO> PhO benzyl chloride PhO, phenoxide
33. Which of the following reaction will go faster if the concentration of the nucleophile is
raised?
H,CO, H
CH3
H, „Br
.CH3
+ осн,
II
-SCH,
.SCH
CH3
H;C,
Br
H.C
II
IV
Br
-SCH3
.SCH
A. I and II
B. Il and IV
C. I and II
D. I, II, and IV
34. Which of the following curve correctly represents SN1 vs SN2?
A
B
5,2
rate
rate
S,1
CHX 1
CHX 1
Alkyl halide
2
Alkyl halide
S,2
rate
rate
CHX
CHX 1"
Alkyl halide
Akyl halide
Transcribed Image Text:33. Which of the following reaction will go faster if the concentration of the nucleophile is raised? H,CO, H CH3 H, „Br .CH3 + осн, II -SCH, .SCH CH3 H;C, Br H.C II IV Br -SCH3 .SCH A. I and II B. Il and IV C. I and II D. I, II, and IV 34. Which of the following curve correctly represents SN1 vs SN2? A B 5,2 rate rate S,1 CHX 1 CHX 1 Alkyl halide 2 Alkyl halide S,2 rate rate CHX CHX 1" Alkyl halide Akyl halide
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Selection Rules for Pericyclic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY