2. You are given an electrochemical cell where the chemical reaction involves a silver complex, and a silver metal bar is provided as the positive electrode. The electrochemical potential for this cell is given by a. b. E=Fº 1 [Ag] -0.0592(volts)-log- Ag /Ag For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20 volts. Find the silver electrode potential EAA- The same cell from (a) will be used to measure the electrochemical potential for a new silver complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver concentration for this new silver complex at a chemical equilibrium state?

Chemical Principles in the Laboratory
11th Edition
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Chapter32: Voltaic Cell Measurements
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2.
You are given an electrochemical cell where the chemical reaction involves a silver complex, and a
silver metal bar is provided as the positive electrode. The electrochemical potential for this cell is
given by
a.
b.
E=Eº
1
[Ag]
-0.0592 (volts).log-
Ag /Ag
For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20
volts. Find the silver electrode potential EºAg-Ag.
The same cell from (a) will be used to measure the electrochemical potential for a new silver
complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver
concentration for this new silver complex at a chemical equilibrium state?
Transcribed Image Text:2. You are given an electrochemical cell where the chemical reaction involves a silver complex, and a silver metal bar is provided as the positive electrode. The electrochemical potential for this cell is given by a. b. E=Eº 1 [Ag] -0.0592 (volts).log- Ag /Ag For a test solution with a silver concentration of 0.001 M, the electrochemical cell potential is 0.20 volts. Find the silver electrode potential EºAg-Ag. The same cell from (a) will be used to measure the electrochemical potential for a new silver complex in equilibrium. If the measured cell potential is 0.324 volts, what is the silver concentration for this new silver complex at a chemical equilibrium state?
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