5) Consider each pair of structures below; indicate which one the species are[1] Constitutional isomers:[2] Enantiomers:[3] Diastereomers:[4] Identical:(B) H,N.HO.(A)FOHOH(D)HO.(C)HO.NH2

Constitutional or structural isomers are compounds with the same molecular formula but different…

Answered: [1] Constitutional isomers: [2]…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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5B. Are the pairs of structures shown below constitutional isomers, enantiomers, diastereomers, or the same? What is the degree of unsaturation for the compound in entry (e)? (a) (b) Me Me (c) F. H3C. ČH3 (e) (f) Et. ОН ОН Et Degree of unsaturation =
5) What is the relationship between each of the following pairs of molecules? Are the underlined answers correct? Explain. Br and Br (Identical Not Isomers Enantiomers Diastereomers I dentical the pos.tion of methul and Bromine becaure are at I and 3, Axial position. (b) Not Isomers Identical Enantiomers Diastereomers Br Br Br and Br (c) CHO CHO H OH HO--H COOH Not Isomers HO-H HO--H ČOOH Enantiomers Diastereomers Identical and (d) Br Enantiomers Diastereomers Not Isomers and Identical Br
3), compounds, enantiomers, diastereomers, or constitutional isomers). The same answer can be used more than once. For the following pairs of compounds, indicate the relationship (identical (a) (b) H H H HO CO,Me MeO,COH NH2 NH2 H. HN -NH2 MeO,cT'OH H. HOTCOME H (c) H CHCH3 (d) CH3 Br. H H он Br- -CH,CH, Br H +H H- Br -H H H HO- -H CH3 H3C- Br -Br ČH3 ČH3 3
Identify the relationship between the following pair of structures by describing them as represting enantiomers, diastereomers, constitutional isomers or two molecules of the same compounds (a) (c) H CH3 Br. CH3 Br f-f and Filmas H H CH3 H F Oll H CHO Br X-X ²=-= -OH HO and and H Br H- F C(O)CH, H (b) CH3 (d) H- and HO CHO -H -OH C(O)CH3
What is the relationship between the following pairs of structures? H₂C CH3 H H H H and H H3C CH3 CH3 CH3 H₂C OH H3CH CH₂CH3 CH3 and HO CH₂CH3 H II and III I A. (1) The same molecule, (II) The same molecule, (III) Diastereoisomers B. (1) Diastereoisomers, (II) Enantiomers, (III) The same molecule C. (1) Constitutional isomers, (II) The same molecule, (III) Enantiomers D. (1) The same molecule, (II) Enantiomers (III) Diastereoisomers E. (1) Constitutional isomers, (II) The same molecule, (III) Constitutional isomers
4. What is the relationship between these molecules? (Enantiomers, diastereomers, constitutional isomers or identical compounds) (a) CH3 CH3 OH OH (b) H3C Br H CH2CH3 CH3 -Br 去 H- CH2CH3 (c) H CH3 -CH3 H H CH3 H CH3 1
11. Which of these molecules are meso isomers? H Cl CL Cl I (A) I only (C) III only H Cl CI II H/H CI III (B) II only (D) I and II only
3. For each of the following pairs of structures identify the stereochemical relationship as identical, constitutional isomers, enantiomers or diastereomers. (^- a) b) SH H₂C SH CH 3 ၀င်း H₂C CH3 H
Identify if the following pairs of compounds are identical, enantiomers, diastereomers or constitutional isomers. * ОН CN and H;C uNCN INCN H3C H. C HO, (ii) and O (1) Identical; (ii) Enantiomers O (1) Enantiomers; (ii) Diastereomers O (1) Enantiomers; (ii) Enantiomers O (1) Identical; (ii) Identical
Identify the relationship between the following pair of structures by describing them as represting enantiomers, diastereomers, constitutional isomers or two molecules of the same compounds (a) (c) H H₂C H F Br Oll F CH3 Br H and Br. CH3 H and Fumus (d) H H X-X=-= CH3 H CH3 (b) Br HO CHO and -OH H C(O)CH3 and HO H- CHO -H -OH C(O)CH3
Indicate whether each of the following pairs of compounds are identical, enantiomers, diastereomers or constitutional isomers. (i) CH2 HÇ OH HO H. and H;C" H3C" CH (ii) and (ii) СНО CHO H. OH- H HO- and H. -HO- НО -H- CH,OH ČH,OH (iv) ÇH3 H3C. CH3 H. CH3 and H. CI CI H. H.
1. Briefly define the following terms (b) enantiomers. (d) diastereomers. (e) meso-compound 2. Predict the product(s) for the following reactions: (a) (CH3)2CHCH₂CH₂ CH NaBH4 CH3CH₂OH

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[1] Constitutional isomers: [2] Enantiomers: [3] Diastereomers: [4] Identical: (B) H,N HN, HO HO. (A) HO. HO, HO. H2N. (D) HO. (C) NH2 O