NaOCI 1) CH,CO,H : CH;CN : H20 MgBr он 2) H20 C10H180 C12H240 C12H240 major stereoisomer minor stereoisomer base C13HaF203 "Fiflunisal" NSAID Drug produced by Merck in 1971 NC. CN heat C10H12N2 enant #1 C10H12N2 enant #2 show "relative stereochemistry" of the methyl groups in the product for full credit. Two enantiomers are produced, draw one in one box, the other in the other box.

NaOCI 1) CH,CO,H : CH;CN : H20 MgBr он 2) H20 C10H180 C12H240 C12H240 major stereoisomer minor stereoisomer base C13HaF203 "Fiflunisal" NSAID Drug produced by Merck in 1971 NC. CN heat C10H12N2 enant #1 C10H12N2 enant #2 show "relative stereochemistry" of the methyl groups in the product for full credit. Two enantiomers are produced, draw one in one box, the other in the other box.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Give the major organic product(s) of the following. Include stereochemistry when applicable. 1) Nal Br a) 2) NaCN, acetone 1) NaOC(CH3)3, heat d Br 2) BH₂ THF; 3) H,O,, NaOH(aq) b) c) d) c) 2) KOC(CH3)3, heat Copyright University of California Merced 2022 Br 1) NaOH, heat 2) MCPBA 1) KOC(CH3)3, heat 2) H3O+
chem 534 cha Hư OAC H please show stereochemistry H₂ COCH ? H CO₂CH3 O Ac 2. + ? hv 9 40°C 3. H₂ C 4. 0°C Catq Q-0 + [6+4] NGC ?. لك 5. [ V-CO₂CH3 + II NCCN [4+2] C6H5 6. 2 C6H5
CH3man Determine the products for the following reactions (indicate major and minor when appropriate). Show stereochemistry. Josterman CH3 HACH3man . 22 ©2022 an CHE CHCH 22 | Kloster HEM40B W22 ©202 | Klostern NaOEt Br H. Compound#865250 EtOH, Д J Klosterman N22 O Compound#250903 G CompounKlosterrcess o, HEM40B W22 O20 W22 22J Klosterman CH ©2022 J Kloste 2. Zn, ACOH W22 b) rman CHEM4 W22 1. Et,0 armal Compound#903865 CHEM40B W22 C 2. NaOH, H202, Н.о 22| Kosterman 22 I Klos Write your answer in the Answer sheet template.
:) Predict the NAME, STRUCTURE and STEREOCHEMISTRY of the BEST ORGANIC REACTANT or the MAJOR ORGANIC product for the following reactions: CH2 МСРВА, НзО* meso 3,4-hexane diol FoH H+OH CHCH a) (name, str, stereochem) ? HCI b) 3-methyl 1-pentene - ? (name, str, stereochem) c) methylcyclohexane ----Br2, hv------? (name, str, stereochem) 40H d) ? (name, str., stereochem) Os04, water----meso cyclohexane 1,2-diol ----
a) b) O₂N of Draw the product of the first step as well as the second step including stereoisomers OH 1) BH3, THF 2) H3O+ 2) 1) KCN/HCN aja. ,NEt3
H3C₂ Br H₂O a. Enantiopure (1R, 3R)-3-Methylcyclohexanol b. Achiral 1-Methylcyclohexanol C. Racemic mixture (1R, 3R)- and (1S, 3S)-3-Methylcyclohexanol d. Diastereomeric mixture of (1R, 3R)- and (1S, 3R)-3-Methycyclohexanol
Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. 1. H* [-H20] OH HO (вхсеs) он но 2. NalO4 CH3 3. Ph3P=/ он H* [-H20] но. CHa 1. H* (-H20] (еxcess) at OH H3C CH3 но. 2. Ph3P=
1. Draw the intermediates A-C for reactions a and b. Please show the appropriate stereochemistry where necessary. RO hv .. RQ CO₂Me MO,C. Anti-tumour agent Coriolin co₂Me barrelene
Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. 1. H3180* 2. K2CO3 Mel CH3 1. CrO3, H30* H3C HO, 2. DCC, HN A, [-H2O] HO
Determine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistr CH₂CH3 CI Br + CN d. + CH3COOH a. acetone + -OCH3 e. DMF f. b. C. ||||| a ||||| Br H Br CH2CH2CH3 + CH3OH DMSO H CH3 CI Br + OCH₂CH3 + CH3CH₂OH
Draw all stereoisomers formed in each reaction. to [1] CH3LI а. [2] H2O 1m( Culi b. [1] [2] H2O [1] LIAIH4 С. с. [2] H2O [1] mCРBA d. [2] MgBr [3] H2O ..||
O (1) H20, H*; (2) Jones reagent (1) H20, H*; (2) PCC, CH2CI2 (1) conc. H2SO4: (2) Jones reagent O (1) H20, H*; (2) Tollens reagent (1) conc. H2SO4: (2) PCC, CH2CI2 O (1) conc. H2SO4: (2) Tollens reagent