0.2143 grams of an unknown organic acid was dissolved in about 50 mL of water in a 250 mL Erlenmeyer flask and titrated against 0.1000 M NAOH solution using bromothymol blue indicator. 30.60 mL of titrant was used to achieve end point. The melting point range of the unknown is 98-102 °C. Ignition test reveals the compound to be aliphatic. Cerric ammonium nitrate test is also positive. Which of the following is the unknown? Hint: Consult Shriner's table.
Q: A 300-mL aqueous solution containing a 30.0g of compound A is to be extracted with ether. The…
A: Ether and water are two immiscible liquids. When together, these form two layers with ether on top…
Q: Approximately 6 mL of concentrated perchloric acid (72%) was transferred to a bottle and diluted…
A:
Q: Suppose solute A has a distribution coefficient of 1.0 between water and diethyl ether. Demonstrate…
A: Distribution coefficient , K = Concentration of solute in organic phase Concentration of solute in…
Q: A 50.0 ml juice extract is colorimetrically assayed using Nelson's test. One milliliter (1.00 mL) of…
A:
Q: An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double…
A:
Q: a) 0.132g of a pure carboxylic acid (R-COOH) was dissolved in 25.00mL of water and titrated with…
A: (a) The number of moles of NaOH (n) is calculated using equation (1) in which C is the concentration…
Q: 0.75 gm of calcium carbonate is dissolved in 1 liter of distilled water. 100 ml of this standard…
A: 0.75 gm of calcium carbonate is dissolved in 1 liter of distilled water. 100 ml of this standard…
Q: 1.Describe other melting point apparatus that are available for routine analysis. 2. Explain the…
A: Melting point apparatus that are available for routine analyis:-
Q: The Kjeldahl procedure was used to analyze 244 µL of a solution containing 38.1 mg protein/mL. The…
A: In Kjeldahl process nitrogen is estimated by following expression Percentage of…
Q: Since EDTA titration must be done at pH 10, which procedure will help in removing the HCl in the…
A: Answer - EDTA - Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the…
Q: Which of the following would LOWER the purity of the distillate collected from the rubbing alcohol…
A:
Q: For a Kjeldahl analysis: you weighed 0.0312 g unknown dried blood sample and digested it with…
A: This experiment uses Kjeldahl's method to estimate the amount of nitrogen in the given organic…
Q: 0.100 g sample of phthalic acid was dissolved in 100 mL of water. When 25 ml of diethyl ether was…
A: Introduction- Solvent extraction is a process where 2 immiscible solvents are separated along with…
Q: A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant…
A:
Q: Calculate the amount of potassium chloride needed to prepare a 60 mL ORS based on the given…
A:
Q: Compound X was dissolved in a 5-mL volumetric flask. A 1.00-mL aliquot of the compound was placed in…
A: Given, Absorbance = 0.427 Cuvette length = 1.00 cm Molar absorptivity = 6130 M-1 cm-1 Molecular…
Q: What weight of strontium acetate containing 99% Sr(CH3COOH)2.½H2O must be used as sample in an assay…
A: Solution -
Q: standardized by dissolving 0.5005g of CaCO3 (99.00% purity) in 100.0mL. A 10.00-mL aliquot was then…
A: Introduction : Complexometric titration are used to determine the metal ions by use of complex…
Q: freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant…
A: Introduction : EDTA is a polydentate chelating ligand which forms a soluble 1:1 complex with most…
Q: A 50.0 mL juice extract is colorimetrically assayed using Nelson's test. One milliliter (1.00 mL) of…
A: Given: 50 mL of original juice is used. 1 mL of the original solution is used to give absorbance of…
Q: Discuss the significance of the following processes and what constituent is being determined: a.…
A: The significance of the processes and presences of constituent is given below.
Q: Tea leaves were boiled and around 1.00 gram of caffeine were extracted using 175.0 ml of water. if…
A: Given: Amount of caffeine=1 g Volume of caffeine solution=175 mL Portion of dichloromethane=20 mL…
Q: An unknown sample containing moved alkal (NaOH, NaHCO or Na CO) was analyzed using the double flask…
A:
Q: A 50.0 mL juice extract is colorimetrically assayed using Nelson’s test. One milliliter (1.00 mL)…
A: We know that according to Beer-Lambert law, the absorbance of any solution is directly proportional…
Q: An EDTA solution was prepared by dissolving approximately 4 g of the disodium salt in approximately…
A:
Q: A 50.0 mL juice extract is colorimetrically assayed using Nelson’s test. One milliliter (1.00 mL) of…
A: Given: 50 mL of original juice is used. 1 mL of the original solution is used to give absorbance of…
Q: Using the end-group analysis to find molecular weight, 6 mol of 1,4-butanediamine reacted with 6 mol…
A: The polymer formed from the given monomers: H2N-(CH2)4-NHOC-(CH2)4-COOH
Q: When is a PTFE buret used? _________________________________________________________ _…
A: PTFE: Polytetrafluoroethylene is a material from which stopcock is made and fitted into the glass…
Q: volumetric flask. A 1.00-mL aliquot of the compound was placed in a 10-mL volumetric flask and…
A: Here a volumetric flask contains 5 ml of of concentrated solution of compound X. 1ml of the original…
Q: Question 1 Which compound are held by stationary phase ? O O Polar compound Non polar compound A and…
A:
Q: John wanted to determine the protein content of his blood. To do so, he obtained 1.00 mL of blood,…
A: Given data, Volume of sample = 1.0mL Molarity of H3BO3= 0.0150M Volume of H3BO3= 25.0mL = 0.025L…
Q: A certain lipid sample consists of a wax of unknown molecular weight and composition. It is known,…
A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…
Q: The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL…
A:
Q: 6.0 mL of cyclohexanol, 8 mL of 85% phosphoric acid, and 10 drops of sulfuric acid are added to a…
A: The percentage yield can be calculated by the formula = Actual yield x 100 /theoretical yield
Q: Upon screening with TLC (made of silica gel) chromatography using hexane/chloroform (3:1) as eluting…
A: Thin layer chromatography is based on the separation principle. The separation lies on the affinity…
Q: Which of the following would LOWER the purity of the distillate collected from the rubbing alcohol…
A: General chemistry
Q: A 50.0 mL juice extract is colorimetrically assayed using Nelson’s test. One milliliter (1.00 mL)…
A: Given: 50 mL of original juice is used. 1 mL of the original solution is used to give absorbance of…
Q: ATION
A: Now, Below are the methods mentioned evaluating the steps,
Q: an accurately weighed chelometric standard calcium carbonate of 150 mg was used to standardize…
A: "Since you have asked multiple questions, we will solve the first question for you. If you want any…
Q: A mixture of benzoic acid and naphthalene was separated by a liquid-liquid extraction by converting…
A: Here we have to choose the correct option about how can be the benzoic acid can be recovered after…
Q: Determination of the concentration of HCl: Pipette 10 mL of hydrochloric acid and transfer to a 100…
A: Acid-base titration refers to titration reaction in which either of titrant or titrate is a base and…
Q: 1. Basically, when is glass stoppered buret used? ______________________________…
A: Given, 1. Basically, when is glass stoppered buret used? ______________________________…
Q: In the Assay of Sodium Chloride, what is the purpose of adding nitric acid in the solution? It is…
A: As per the guideline, since you have asked multiple questions, we have solved the first question for…
Q: An unknown sample containing mixed alkali (NaOH, NaHCO3, or NazCO3) was analyzed using the double…
A:
Q: A freshwater sample containing Ca2+ and Mg2+ will be analyzed using EDTA titration. The EDTA titrant…
A:
Q: You prepared a stock solution by dissolving a compound with the molar mass of 110.65 in a 100 mL…
A: Given : Molar mass of compound = 110.65 g/mol Final volume of solution = 250 mL = 0.250 L…
Q: Please show all the calculations. I have these information available: 32.00 mL of 1 butanol and…
A:
Q: A sample of Al2(SO4); weighing 7.52-g was dissolved in enough water and diluted to 250.0-mL.…
A: Given: Mass of sample = 7.52 g. The sample is diluted to 250 mL. Volume of diluted sample used =…
Q: Preparation and Standardization of 0.05 M Disodium Ethylenediaminetetraacetate (EDTA) Preparation:…
A: Given question is standardization of EDTA with CaCO3 solution.
Q: her 250.00 mL sample was then treated with NaOH to precipitate Mg(OH)2 and was then titrated at pH…
A:
Step by step
Solved in 3 steps with 3 images
- A 10.00mL sample of alcoholic ethyl acetate was diluted to 100.00 mL. 20.00 mL was aliquoted and mixed with 40.00 mL of 0.04672 M KOH. The resulting mixture was heated for 2 hours. CH3COOC2H5 + OH- → CH3COO- + C2H5OH After cooling, the excess OH was back titrated with 3.41 mL of 0.05042 M H2SO4. Answer the following: Calculate the number of moles of OH- that reacted with ethyl acetate. Calculate the number of moles of ethyl acetate in the 20.00 mL solution. What is the mass of ethyl acetate (FW=88.11 g/mol) in the original 10.00 mL sample?True/False Indicate whether the statement is true or false. Write T if the statement is true while F if statement is false on the before each number 4.Assay of acetic acid in vinegar is an example of proximate analysis 5.Example of variable defects are color, clarity, sheen, cleanliness, smoothness, taste, and presence or absence of a characteristic. 6.Liberation of carbon dioxide during acid-alkali titration renders the analyte acidic BAn unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 311 mL of the standard acid. What is/are the component/s of the sample? O Cannot be determined O NAHCO3 only O NAOH and Na,CO3 O NazCO3 only O NAHCO, and Na2CO3
- Very pure silver nitrate standard reagent requires standardization with primary standard NaCl or KCl True False A water sample was analyzed for the total hardness through the reaction between the sample and EDTA. The data obtained from the experiment are presented below (MM CaCO3 = 100.0869 g/mol): Table 1. Standrdization of the EDTA solution mass of CaCO3 used 0.5467 g Initial burette reading 8.25 mL Final burette reading 16.65 mL Volume consumed 8.40 mL Table 2. Determination of Hardness of Water Volume of water sample 25.00 mL Initial burette reading 15.00 mL Final burette reading 24.00 mL Volume consumed 9.00 mL 23,469 ppm 22,456 ppm 21,290 ppm 23,990 ppmA 0.937-g sample containing Ca²+ was dissolved to produce a 500-mL stock solution. A 50-mL aliquot was then obtained and titrated with 0.029 M EDTA. A volume of 23.15 mL was required to reach the endpoint. Calculate the amount of calcium (in %CaCO3) in the sample. (MW (g/mol): EDTA=292.24; CaCO3 = 100; Ca=40) Express your answer with 2 decimal places and do not encode the units.An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO2 free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 mL of the standard acid. How many millimoles of the components are there in the original solid sample? O 0.28 mmol Na,CO3 O 1.29 mmol NaOH, 0.97 mmol Na2CO3 O 0.103 mmol NaOH, 0.078 mmol NazCO3 O 1.29 mmol Na2CO3, 0.97 mmol NaHCO3 O Cannot be determined
- An unknown sample containing mixed alkali (naoh, nahco3, or na2co3) was analyzed using the double flask method. a 250 mg sample was dissolved in 250 ml co2 free water. a 20.0 ml aliquot of this sample required 11.3 ml of 0.009125 m hcl solution to reach the phenolphthalein end point. another 29.0 ml aliquot of the sample was titrated to the bromocresol green endpoint using 31.1 ml of the standard acid. how many millimoles of the components are there in the original solid sampleA 1.5000-g sample of cereals was analyzed for nitrogen using the Kjeldahl procedure. The receiving flask contained 69 mL of 0.02 M HCl. After the ammonia was collected, the solution was titrated with 0 M NaOH, requiring 11.72 mL to reach the methyl red endpoint. Calculate and percent protein in the sample (f=5.70). Ans. in 3 SFsA 50 mL sample solution containing 8-hydroxyquinoline (MW: 145) was analyzed by adding 25 ml, 0.1 M KBrO3, excess KBr and acidified. The mixture was left for 10 minutes in dark place. After this time KI in excess was added followed by titration with 27.9 mL, 0.05 M thiosulfate standard solution. Write balance equations? What is the percent w/v 8-hydroxyquinoline in sample?
- Following the monograph procedure, a 724-mg of aspirin (MW+180 g/mol) dissolved in 18.5 ml of cold neutralized alcohol. This solution was then initially titrated with 0.101 N sodium hydroxide solution, then later neutralized with 0.104 sulfuric acid. 1. What is the milliequivalent weight consumed by the acidic titrant? a. 1.5392 g-meq b. 2.0907 g-meq c. 1.4948 g-meq d. 2.1528 g-meq 2. What is the milliequivalent weight consumed by the basic titrant? a. 5.8656 g-meq b. 1.5392 g-meq c. 5.6964 g-meq d. 1.4948 g-meq 3. What is the difference of milliequivalent weight consumed in the reaction? a. -4.1572 g-meq b. 4.3708 g-meq c. 0.5515 g-meq d. 4.1572 g-meqAn unknown sample containing mixed alkali (NaOH / NaHCO3 / Na2CO3) was analyzed using the double titration method. A 250-mg sample was dissolved in 250-mL CO2 free water. A 20.0-mL aliquot of this sample required 11.3-mL of 0.009125M HCl solution to reach the phenolphthalein endpoint. Another 20.0-mL aliquot of the sample was titrated to the bromocresol green endpoint using 31.1-mL of the standard acid. What is/are the component(s) of the sample? How many mmol of the components are there in the original solid sample?Following the monograph procedure, a 724-mg of aspirin (MW=180 g/mol) dissolved in 18.5 ml of cold neutralized alcohol. This solution was then initially titrated with 0.101 N sodium hydroxide solution, then later neutralized with 0.104 sulfuric acid. 1. What is the total volume (mL) of excess titrant used in the titration? a. 56.400 mL b. 52.000 mL c. 44.600 mL 2. What is the milliequivalent weight consumed by the acidic titrant? a. 1.5392 g-meq b. 2.0907 g-meq c. 1.4948 g-meq d. 2.1528 g-meq 3. What is the milliequivalent weight consumed by the basic titrant? a. 5.8656 g-meq b. 1.5392 g-meq c. 5.6964 g-meq d. 1.4948 g-meq 4. What is the difference of milliequivalent weight consumed in the reaction? a. -4.1572 g-meq b. 4.3708 g-meq c. 0.5515 g-meq d. 4.1572 g-meq 5. What is the percentage purity of the sample? 6. What is the titer value (mg) based from the specific type of titration?