Concept explainers
(a)
Interpretation:
The formula of
Concept Introduction:
Alcohols:
Organic compounds that contain a hydroxyl group that is covalently bonded to a carbon atom
- 1) Primary alcohol: One organic group attached to hydroxyl atom.
- 2) Secondary alcohol: Two organic groups bonded to hydroxyl atom.
- 3) Tertiary alcohol: Three organic groups bonded to hydroxyl atom.
The general formula for alcohol is,
Primary alcohol:
Secondary alcohol:
Tertiary alcohol:
Phenol:
Organic compounds those in which, a hydroxyl group is attached directly to an
(a)
Answer to Problem 11D.7E
The formula of
Explanation of Solution
The structure of
One-chlorine substituent is attached to the benzene ring in the first position and the hydroxyl group is attached to the benzene ring in second position. The formula of
(b)
Interpretation:
The formula of
Concept Introduction:
Refer to part (a).
(b)
Answer to Problem 11D.7E
The formula of
Explanation of Solution
The structure of
The parent chain is pentane. A hydroxyl group is present at the carbon third position and one methyl group is present in the carbon second position. The formula of
(c)
Interpretation:
The formula of
Concept Introduction:
Refer to part (a).
(c)
Answer to Problem 11D.7E
The formula of
Explanation of Solution
The structure of
The parent chain is hexane. A hydroxyl group is present at the carbon first position and two methyl groups are present in the carbon second position and fourth position. The formula of
(d)
Interpretation:
The formula of
Concept Introduction:
Refer to part (a).
(d)
Answer to Problem 11D.7E
The formula of
Explanation of Solution
The structure of
The parent chain is butane. A hydroxyl group is present at the carbon second position and one methyl group is present in the carbon second position. The formula of
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Chapter 11 Solutions
Chemical Principles: The Quest for Insight
- Draw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methyl-amine; (b) butanoic acid and 2-propanol; (c) Formica acid and 2-methyl-1-propanol.arrow_forwardDraw the organic product formed when the following compounds undergo a substitution reaction:(a) acetic and 1-hexanol; (b) propanoic acid and dimethylamine; (c) ethanoic acid and dimethylamine.arrow_forwardGive the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forward
- 5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forwardDraw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methylamine; (b) butanoic acid and 2-propanol; (c) formic acid and 2-methyl-1-propanol.arrow_forwardWrite the condensed structural formula for each of thefollowing compounds: (a) 2-ethyl-1-hexanol, (b) methylphenyl ketone, (c) para-bromobenzoic acid, (d) butyl ethylether, (e) N,N-dimethylbenzamide.arrow_forward
- Draw condensed formulas for the following compounds:(a) 3-ethyl-3-methyloctane; (b) 1-ethyl-3-propylcyclohexane (also draw a carbon-skeleton formula for this compound); (c) 3,3-diethyl-1-hexyne; (d) trans-3-methyl-3-heptene.arrow_forward(1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forward1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forward
- (a) What structural feature is associated with each type of hydrocarbon: alkane, cycloalkane, alkene, and alkyne?(b) Give the general formula for each type.(c) Which hydrocarbons are considered saturated?arrow_forward5) Provide complete and balanced chemical reactions for the following. Write the formula and the name of the alcohol that when dehydrated, gives rise to the following alkenes. Give complete reactions. (а) СH-CH,CH-CH-CHCH-CHa (b) • 3-ethyl-1-hexanol is a primary alcohol. Give the two complete oxidation reactions using potassium permanganate.arrow_forwardTRUE OR FALSE (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic…arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning