Answered: Draw the Lewis structures for [ClF2] +…

Draw the Lewis structures for [ClF2] + and [ClF2] – . How many bonding pairs and lone pairs surround the Cl atom in each ion?

General Chemistry - Standalone book (MindTap Course List)

11th Edition

ISBN:9781305580343

Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Chapter9: Ionic And Covalent Bonding

Section: Chapter Questions

Problem 9.24QP: Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo...

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Concept explainers

Actinides

The elements in which the extra electron tends to enter the 5f-orbitals of (n–2)th main shell are considered 5f-block elements. They are also named actinides. Actinides include 15 elements, from atomic number 89 to 103.

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Draw the Lewis structures for [ClF2] + and [ClF2] – . How many bonding pairs and lone pairs surround the Cl atom in each ion?

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Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?
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Consider the following ion: BrO3 − . a) Show the full electron configuration for Br. b) Draw the most correct Lewis structure for BrO3 − and briefly explain why your Lewis structure is correct. c) If the structure is stabilised by resonance, draw at least one of the possible resonance forms. If it is not stabilised by resonance, briefly explain why. d) What is the electronic geometry of BrO3 − ? What is its molecular shape? e) Does BrO3 − have a dipole moment? Briefly justify your answer. f) On average, would you expect IO3 − to have longer or shorter bonds than BrO3 − ? Briefly explain your answer. g) Which of the following molecules would you expect to have the lowest vapour pressure? Briefly explain your choice. h) What is the molecular formula for Compound C? What is the empirical formula for Compound C?
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