a. Calculate the molar solubility of AgBr in pure water.Ksp for AgBr is 5.0×10-13. b. Calculate the molar solubility of AgBr in 3.0 M NH3. The overall formation constant for Ag(NH3)2+is 1.7×107, that is, Ag+(aq) + 2NH3(aq) → Ag(NH3)2+(aq) K = 1.7×107 . c. Compare the calculated solubilities from parts a and b. Explain any differences. d. What mass of AgBr will dissolve in 250.0 mL of 3.0 M NH3? e. What effect does adding HNO3 have on the solubilities calculated in parts a and b?

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section: Chapter Questions
Problem 102IL: Each pair of ions below is found together in aqueous solution. Using the table of solubility product...
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a. Calculate the molar solubility of AgBr in pure water.Ksp for AgBr is 5.0×10-13.

b. Calculate the molar solubility of AgBr in 3.0 M NH3. The overall formation constant for Ag(NH3)2+is 1.7×107, that is,

Ag+(aq) + 2NH3(aq) → Ag(NH3)2+(aq) K = 1.7×107 .

c. Compare the calculated solubilities from parts a and b. Explain any differences.

d. What mass of AgBr will dissolve in 250.0 mL of 3.0 M NH3?

e. What effect does adding HNO3 have on the solubilities calculated in parts a and b?

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