Your titration experiment included phosphoric acid, liqid starch, and Iodine-Potassium-Iodide (IKI) solution. The following information is given: iodine is too weakly colored to act as an effective primary indicator, but it is enhanced by its interaction with stach in a solution. The secondary indicator you will use in this experiment is iodine-starch complex. Iodine-potassium-iodide is the titrant.  What acted as the primary indicator in this experiment? The secondary indicator? What was the role of the phosphoric acid? What would happen if you forgot to add it, or added a base instead?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 67CP
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Your titration experiment included phosphoric acid, liqid starch, and Iodine-Potassium-Iodide (IKI) solution. The following information is given: iodine is too weakly colored to act as an effective primary indicator, but it is enhanced by its interaction with stach in a solution. The secondary indicator you will use in this experiment is iodine-starch complex. Iodine-potassium-iodide is the titrant. 

  1. What acted as the primary indicator in this experiment? The secondary indicator?
  2. What was the role of the phosphoric acid? What would happen if you forgot to add it, or added a base instead?
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