You have a solution of nitrous acid (HNO2). What effect will addition of sodium nitrite (NaNO2) have on the pH of the solution? Ka for nitrous acid = 4.5 ´ 10-4
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Q: What is the hydronium ion concentration in 0.275 M nitrous acid? Ka= 7.1x10^-4
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Q: 11. What is the pH of 0.25 M NaNO, solution? 2 [Ka of HNO, = 4.0 x 10“] * Points 5.6 6.0 3.7 9.0 8.4
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Q: What is the percent ionization of nitrous acid in a solution that is 0.230 M in nitrous acid (HNO2)…
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A: Given: [H+ ] = 0.001 M And the Ka of HA = 1.0 × 10-5
Q: A 0.1000 M solution of a weak acid, HA, is 3.0% dissociated. Determine the value of Ka for the weak…
A: Given : Concentration of weak acid HA = 0.1000 M And the percent of HA dissociated = 3.0 %.
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Q: Calculate the pH if 0.30M Acetic Acid, with Ka = 1.8 x 10-5 is added to 0.20M Sodium Acetate.
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Q: 8. What is the pH of a 0.20M solution of sodium acetate? The K, for acetic acid is 1.8 x 10-5 ?
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Q: You have 500. mL of a solution containing 0.20 M acetic acid (CH3COOH) and 0.30 M sodium acetate…
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Q: Phosphoric acid is a triprotic acid (Kal = 6.9 x 10-3, K2 = 6.2 x 10-8, and Ka3 = 4.8 x 10-13). To…
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Q: Determine the pH of a solution prepared by dissolving 0.35 mole of ammonia chloride in 1.0l of 0.25M…
A: To determine the pH of the solution.
You have a solution of nitrous acid (HNO2). What effect will addition of sodium nitrite (NaNO2) have on the pH of the solution? Ka for nitrous acid = 4.5 ´ 10-4
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- The hydrogen phthalate ion, C8HsO4, is a weak acid with Ka = 3.91 106. C8H5O4(aq)+H2O(l)C8H4O42(aq)+H3O+(aq) What is the pH of a 0.050 M solution of potassium hydrogen phthalate. KC8H5O4? Note: To find the pH for a solution of the anion, we must take into account that the ion is amphiprotic. It can be shown that, for most cases of amphiprotic ions, the H3O+ concentration is [H3O+]=Ka1Ka2 For phthalic acid, C8H6O4 is Ka1 is 1.12 103, and Ka2 is 3.91 106.What are the equilibrium concentrations of acetic acid, the acetate ion, and H3O+ for a 0.10 M solution of acetic acid (K2 = 1.8 105)? What is the pH of the solution?The pigment cyanidin aglycone is one of the anthocyanin molecules that gives red cabbage (Brassica oleracea var. capitata f. rubra) its characteristic red coloration. Many chemistry students have used this red cabbage indicator to study acid-base chemistry. Estimate tire pH range at which cyanidin agly-cone shows a color change. Anth-H(aq) Anth(aq) + H+ (aq) Ka = 1.3 107
- Weak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/AWhat are the major species in solution after NaHSO4 is dissolved in water? What happens to the pH of the solution as more NaHSO4 is added? Why? Would the results vary if baking soda (NaHCO3) were used instead?For conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)
- Acrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?Complete each of these reactions by filling in the blanks. Predict whether each reaction is product-favored or reactant-favored, and explain your reasoning. (a) _________ (aq) + Br(aq) NH3(aq) + HBr(aq) (b) CH3COOH(aq) + CN(aq) ________ (aq) + HCN(aq) (c) ________ (aq)+H2O () NH3(aq) + OH(aq)The simplest amino acid is glycine, H2NCH2CO2H. The common feature of amino acids is that they contain the functional groups: an amine group, -NH2, and a carboxylic acid group, -CO2H. An amino acid can function as either an acid or a base. For glycine, the acid strength of the carboxyl group is about the same as that of acetic acid. CH3CO2H, and the base strength of the amino group is slightly greater than that of ammonia, NH3. (a) Write the Lewis structures of the ions that form when glycine is dissolved in 1 M HCl and in 1 M KOH. (b) Write the Lewis structure of glycine when this amino acid is dissolved in water. (Hint: Consider the relative base strengths of the -NH2 and -CO2- groups.)
- Magnesium hydroxide, Mg(OH)2, is the active ingredient in die antacid TUMS and has a Ksp value of 8.9 1012. If a 10.0-g sample of Mg(OH)2 is placed in 500.0 mL of solution, calculate the moles of OH ions present. Because the Ksp value for Mg(OH)2 is much less than 1, not a lot of solid dissolves in solution. Explain how Mg(OH)2 works to neutralize large amounts of stomach acid.You add 0.979 g of Pb(OH)2 to 1.00 L of pure water at 25 C. The pH is 9.15. Estimate the value of Ksp for Pb(OH)2.Most naturally occurring acids are weak acids. Lactic acid is one example. CH3CH(OH)CO2H(s)+H2O(l)H3O+(aq)+CH3CH(OH)CO2(aq) If you place some lactic acid in water, it will ionize to a small extent, and an equilibrium will be established. Suggest some experiments to prow that this is a weak acid and that the establishment of equilibrium is a reversible process.
