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Write the radical polymerisation mechanism for following reaction Ŕ H ₂ C = C - <=CH₂ BY Cl

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter31: Synthetic Polymers

Section31.2: Stereochemistry Of Polymerization: Ziegler–natta Catalysts

Problem 4P

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Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

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Write the radical polymerisation mechanism for following reaction
Ŕ
?
H₂₂ C = C - <=CH₂
с
By cl

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