Answered: Write the d orbital configurations and…

Write the d orbital configurations and use the Tanabe-Sugano diagrams to identify the ground term of (a low-spin [Rh(NH;)6]**, (b) [Ti(OH2),]³*, (c) high-spin [Fe(OH2)6]³+

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy

Section: Chapter Questions

Problem 19.12QE

See similar textbooks

Related questions

Q: Describe the bonding situation in charge-transfer complexes

Q: Which of the following pairings is incorrect in describing the spin states of d electrons in…

A: ANSWER IS

Q: True or false In the coordination compound [Mn(OH2)6]SO4, the complex cation is octahedral and…

A: Atomic number of Mn = 25 Atomic number of Pt = 78

Q: In 2001, chemists at SUNY-Stony Brook succeeded in syn-thesizing the complex trans-[Fe(CN)4(CO)2]2-,…

A: The compounds where metal ion is the central metal and molecules that can share their electron with…

Q: Write the state of hybridisation, the shape and the magnetic behaviour of the following complex…

A: (i) [Cr(NH3)4Cl2]Cl: Hybradisation of [Cr(NH3)4Cl2]Cl is d2sp3 Geometry of [Cr(NH3)4Cl2]Cl is…

Q: Name the following coordination compound below K2[NbF,] H[Mo(CO),Br;] i. ii. iii.…

A: Coordination compound have a metal ion that is bonded to ligands by coordination bonds.…

Q: The complexes [V(H2O)6]3+ and [VF6]3- are both known. What gives rise to the colors of these…

A: The striking colors exhibited by the complexes are caused due to excitation of an electron from…

Q: Sketch the structure of all possible isomers of a coordination compound of the type (MAA)3 as in the…

A: Isomerism :- The phenomenon of existence of compounds with same molecular formula but different…

Q: For the low spin coordination compound [Fe(en)2Cl]Cl, identify the Oxidation number of iron

A: Note : I think the complex should [Fe(en)2Cl2]Cl. So I'm giving answer for both the complex.

Q: Draw the structure of the following complexes: a. [Co(en)2(NH3)CI]2+ b.…

Q: A coordination compound has been determined to be composed of 18.4% Co, 26.6% NH3, 30.0% SO4², and…

A: When ions present in side the coordination sphere, then it can't react as it remains as coordinated…

Q: Oxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the…

A: Hemoglobin is a very important compound in human body. It acts as oxygen carrier from lungs to body.…

Q: The coordination complex [Cr(CO)6] forms colorless, diamagnetic crystals that melt at 90 °C. Given…

Q: • Give the formulas of these coordination complexes: • a. Tris(acetylacetonato)iron(III) • b.…

A: as per our guidelines we are supposed to answer only 3 sub- parts. Please repost others. a.…

Q: What is the coordination number of the central metal in [Cr(acac)3] ? The acac ligand can be…

A: Coordination number of the central metal which is Chromium in [Cr(acac)3] is 6.

Q: Write the name, the state of hybridization, the shape and the magnetic behaviour of the following…

A: Magnetic behavior has 2 terms Paramagnetic mean having unpaired electrons Diamagnetic means having…

Q: Draw the structure of the complex, [Ni(NH3)6][BF4]2, including approximate bond angles (in °).…

A: The objective of the question is to draw the given complex and write the angle and geometry.

Q: Draw the crystal-field energy-level diagrams and showthe placement of d electrons for each of the…

A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: What coordination isomer can be written for [Co(en)3][Cr(ox)3]?

A: Two coordination isomers are possible:- Answer [Co(en)3][Cr(ox)3] and [Cr(en)3][Co(ox)3] are the…

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…

A: a) The given compound is [V(H2O)6]3+ The Oxidation state of ‘V’ is +3. The electronic configuration…

Q: 3+ (d) [Cr(OH)2]6* ions are pale blue-green but chromate (Cr,O,) ion is an intense yellow in colour.…

Q: If one mole of PtCl4-5NH3 reacts with AgNO, to produce three moles of AgCl(s), how can the formula…

A: The molecular formula of the given coordination compound is = PtCl4.5NH3 The coordination sphere in…

Q: The complexes [V(H2O)6]3+ and [VF6]3- are both known.(a) Draw the d-orbital energy-level diagram for…

A: SOLUTION: Step 1: a. The orbital energy level diagram for V(III) octahedral complex is as follows:

Q: The coordination complex [Cr(CO)6] forms colorless, diamagnetic crystals that melt at 90 °C. Given…

A: A substance is diamagnetic in nature if all the electrons are paired. For a complex to be colored,…

Q: Given the following coordination compounds; Compound R =[Pt(NH3)a(OH)2]SO4 Compound S=…

A: Isomers are those compound that have same molecular formula but different structural formula. The…

Q: Pyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a…

A: Ligands Ligands in the coordinated complex is the ion or neutral molecule that act as the lewis base…

Q: Describe the state of hypridisation , shape and the magnetic behavior of the following complexes :…

Q: A coordination compound has been determined to be composed of 18.4% Co, 26.6% NH3, 30.0% SO4 , and…

A: A co-ordination compound is a compound containing a central metal atom bound to ligands. The central…

Q: Give the systematic name of this coordination compound. K,[Fe(CN),l

A: As formula has 6 CN So, hexacyano Fe so, ferrate(III)

Q: How many unpaired electrons are there in the low-spin state of Co2+ in an tetrahedral field?

A: In any "coordination complex" electrons get filled depending upon ligand nature. If "strong ligand"…

Q: SAIC Ex7.1 Name and draw structures of the following complexes: a) [Ni(CO)4], b) [Ni(CN)4] , v)…

A: a) [Ni(CO)4] - Tetracarbonylnickel (0) b) [Ni(CN)4]2- - Tetracyanonickelate (II) ion c) [CoCl4]2-…

Q: 1)Use the nature of the bonding in d-transition metal complexes with CO to explain why HCo(CO)4…

Q: For the hexacyanoferrate(III) ion, [Fe(CN)6]^3- calculate the crystal field stabilization energy…

A: Given : We have to calculate the CFSE for [Fe(CN)6]3- .

Q: Use your knowledge of electronic transitions in coordination compounds to justify why the compound…

A: If a sample absorbs all wavelengths of visible light, none reaches our eyes from that sample, and…

Q: Mention the types of structural isomerism present in metal complexes and indicate to which of them…

A: Coordination isomerism is a form structural isomerism in which the composition of coordination…

Q: In what directions do you expect the bond length andvibrational frequency of a free CO molecule to…

A: Interpretation - In what directions the bond length and vibrational frequency of a free CO molecule…

Q: y8gngu. Amino acids can act as ligands toward transition metal ions. The simplest amino acid is…

A: Ligands are the electron donating neutral or anionic group that donates the atleast one electron…

Q: Explain the following observations :(i) Copper atom has completely filled d orbitals (3d10) in its…

A: The elements in which the last electron is filled in d sub shell are known as transition elements.

Q: Describe how magnetism in lanthanides series arises

A: Instead making this explanation complex let me explain you in very simple language. As we know that…

Q: 4. *The three complexes [Co(NH3)6]3*, [Co(NH3)5(H20)]³*, and [CoF6]3- are colored red, yellow, and…

A: The question is based on the concept of coordination compounds. We have to assign different colours…

Q: Give the systematic name of this coordination compound. [(en), ]Cl, systematic name:

A: Rules for naming complex compounds :- In coordination sphere ligands are named fist in alphabetical…

Q: How many unpaired electrons are there in the high-spin state of Co2+ in an tetrahedral field?

A: Electronic configuration of Co is [Ar] 3d7 4s2 Thus, electronic configuration of Co2+ is [Ar] 3d7

Q: When cobalt(II) chloride is treated, under certain condition, with the bidentate ligand,…

A: Coordination number is defined as the number of ligands that are attached to a metal in a complex…

Q: why d³ and d⁸ high spin complexes are more stable than other configurations?

A: High spin complexes: According to crystal field theory, two types of complexes are formed. High spin…

Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…

Q: For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify(i) the oxidation number of…

A: Organometallic compounds contains a bond between a metal and a carbon atom of an organic ligand.…

Q: One of the more famous species in coordination chemistry is the Creutz-Taube complex: 5+ (NH3);RuN…

A: (a). There is one metal ion in the complex i.e; Ru. It exhibits two different oxidation states: 1st…

Q: Why Co+2 coordinate complexes are more stable than Fe+2 complexes?

A: A coordination complex is made up of a central atom or ion, which is typically metallic and is…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

Write the d orbital configurations and use the Tanabe-Sugano diagrams to identify the ground term of (a)
low-spin [Rh(NH;)6]**, (b) [Ti(OH2)6]³*, (c) high-spin [Fe(OH;)6J**

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ions
[Cr(H2O)6]³* ions are pale blue-green but the chromate ion CrO,²- is intense yellow. Characterize the origins of the transitions and explain the relative intensities.
How many unpaired electrons do you predict for the tetrahedral[MnCl4]2 - ion?(a) 1, (b) 2, (c) 3, (d) 4, (e) 5.
Pyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a monodentate or bidentate ligand? (b) For the equilibrium reaction [Ru(py),(bipy)]²+ + 2 py = [Ru(py),J* + bipy would you predict the equilibrium constant to be larger or smaller than one?
The cobalt carbonyl complex, Co2(CO)8, undergoes an oxidation with hydrogen gas to form a monomeric metal hydride product, HCo(CO)4. The resulting complex could have one of three possible structures, so an infrared spectrum was obtained. If the spectrum has 12 observable bands overall, what is the likely structure?
Calculate the spin multiplicity for [Ni(H2O)6]2+
Determine the oxidation state of the coordinated metal atom in each of the following compounds:(a) K[Co(NH3)2(CN)4]; (b) Os(CO)5; (c) Na[Co(OH2)3(OH)3].
The orbital occupancies for the d orbitals of several com-plex ions are diagrammed below. (a) Which diagram corresponds to the orbital occupancy of thecobalt ion in [Co(CN)₆]³⁻? (b) If diagram D depicts the orbital occupancy of the cobalt ionin [CoF₆]ⁿ, what is the value of n? (c) [NiCl₄]²⁻ is paramagnetic and [Ni(CN)₄]²⁻ is diamagnetic.Which diagrams correspond to the orbital occupancies of thenickel ions in these species? (d) Diagram C shows the orbital occupancy of V²⁺ in the octa-hedral complex VL₆. Can you determine whether L is a strong-or weak-field ligand? Explain.
Give systematic names for the following formulas:(a) K[Ag(CN)2] (b) Na2[CdCl4] (c) [Co(NH3)4(H2O)Br]Br2
One of the following solids is yellow, and the other is green: Fe(NO3)2 · 6 H2O; K4[Fe(CN)6] 3 H2O. a) Illustrate the d orbitals of the metal center of the given solids. b) Identify which of them is yellow or green using the diagram of their orbitals and spectrochemical series.
Draw the octahedral crystal field d orbital splitting diagrams for [Fe(OH2)6] 2+ and [Fe(CN)6] 3. Indicate if the diagrams are high spin and low spin. give the names of the d-orbitals (dxz, dxy, dzy, dz2, dx2 - y2) label the appropriate orbital sets eg* and t2g and show how the electrons populate the diagram. (Hint: Pairing energy for 3d orbitals Fe 2+ = 29875 cm-1, Fe 3+ = 19150 cm-1; delta OH for Fe(OH2)6]2+ = 14300 cm-1 and delta OH for [Fe(CN)6]3 - is 35000 cm-1
Name the compounds (a) [Cr(H2O)4Cl2]Cl, (b) K4[Ni(CN)4].