Write Lewis structures for each molecule or ion. Include reso-nance structures if necessary and assign formal charges to allatoms. If necessary, expand the octet on the central atom tolower formal charge.a. SO,2-b. HSO,c. SO3d. BrOz

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Chemistry

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ISBN:9781133611097

Author:Steven S. Zumdahl

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Chapter8: Bonding: General Concepts

Section: Chapter Questions

Problem 7RQ: Define formal charge and explain how to calculate it. What is the purpose of the formal charge?...

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Define formal charge and explain how to calculate it. What is the purpose of the formal charge? Organic compounds are composed mostly of carbon and hydrogen but also may have oxygen, nitrogen, and/or halogens in the formula. Formal charge arguments work very well for organic compounds when drawing the best Lewis structure. How do C, H, N, O, and Cl satisfy the octet rule in organic compounds so as to have a formula charge of zero?
The molecular ion S3N3 has the cyclic structure All SN bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is 0.375 and on each S atom is +0.041 . Show that this result is consistent with the overall +1 charge on the molecular ion.
Write the Lewis structure for each ion. Include resonance structures if necessary and assign formal charges to all atoms. If necessary, expand the octet on the central atom to lower formal charge.a. PO43- b. CN- c. SO3 2- d. ClO2 -
Write Lewis structures for each molecule or ion. Include resonance structures if necessary and assign formal charges to all atoms. If necessary, expand the octet on the central atom to lower formal charge.a. SO42 - b. HSO4- c. SO3 d. BrO2-
Please draw the Lewis structure (with formal charges) of the indicated chemical species: 1. ) HBrO2 2.) BrO3- 3.) SeO4^2- 4.) HPO4^2- 5.) ClO2- 6.) HBrO3 7.) BrO2- 8.) IO3- 9.) HSeO4- 10.)HIO2 11.) H2SeO4
Write Lewis structures for each molecule or ion. Include resonance structures if necessary and assign formal charges to all atoms. If you need to, expand the octet on the central atom to lower formal charge.a. SO42- b. HSO4 - c. SO3 d. BrO2-
Write a Lewis structure that obeys the octet rule for each molecule or ion. Include resonance structures if necessary and assign formal charges to each atom. a. SeO2 b. CO32- c. ClO- d. NO2-
3. Consider the Lewis structure for the polyatomic oxyanion shown here, where X is an element from the third period (Na - Ar). By changing the overall charge, n, from 1- to 2- to 3- we get three different polyatomic ions. For each of these ions a. identify the central atom, X; b. determine the formal charge of the central atom, X; c. draw a Lewis structure that makes the formal charge on the central atom equal to zero. :Ö: :0– :0: -Ö:
4. The following are valid Lewis structures for CH3SOCH3. Label the formal charges and circle the best Lewis structure. H :ö: H H :0 H a) H-C=S-C-H b) Н—С—S— С-н H. H. H. H. Н :0: Н H :ö: H d) H-C=$-C-H c) Н—С—$—С-н H. H. H H
Write the Lewis structure for each ion. Include resonancestructures if necessary and assign formal charges to all atoms. Ifnecessary, expand the octet on the central atom to lower formalcharge.a. PO43- b. CN- c. SO32- d. ClO2-
H зн. + H:Y: H The Lewis representation above depicts a reaction between hydrogen (blue) and a main-group element from group | (red). In this representation, each Y atom needs bond(s) with atoms of H. ]electron(s) to complete its octet, and gains these electrons by forming There are| Junshared electron pair(s) and | bonding electron pair(s) in the product molecule. The bonds in the product are |
63. Write a Lewis structure that obeys the octet rule for each mole- cule or ion. Include resonance structures if necessary and assign formal charges to each atom. MISSED THIS? Read Section 10.8; Watch KCV 10.8, IWE 10.7 b. CO3²- d. NO₂ a. SeO2 c. CIO Write a Louis structure that obos the octet rule for each ion.

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Write Lewis structures for each molecule or ion. Include reso- nance structures if necessary and assign formal charges to all atoms. If necessary, expand the octet on the central atom to lower formal charge. a. SO,2- b. HSO, c. SO3 d. BrOz