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- 82. The space shuttle Orbiter utilizes the oxidation of methylhy- drazine by dinitrogen tetroxide for propulsion: 4N₂H3CH3(1) + 5N₂O4 (1) 12H₂O(g) + 9N₂(g) + 4CO2(8) Calculate AH for this reaction. ▬▬▬▬▬▬▬▬▬▬= (b) Calculate the pH of 0.0005 mol dm³ ethanoic acid when its pK 4.75 CH₂COOH(aq) à CH₂COO (aq) + H* (aq) K₂ II pH =6.) Predict the product of the following chemical reactions and state where the product (waste) should the waste should be disposed: Example: он 1. Nallif, ethanol 2. 10 CH,CH,CH,CH CH,CH,CH,CH H Butanal 1-Butanol Waste: G704 (Non-halogenated organic solvents) 1. Nalil, ethanal a.) Cyclohexanecarbaldehyde 2 110 b.) Sodium Flouride + 3-iodo-3-methylpentane (hìnt: substitution or elimination?) H,O c.) Benzoic acid + Phenol PCC d.) 3-pentanol H.CrO> e.) Cyclohexylmethanol
- 23. What is the correct form of the equilibrium constant Kc for the reverse reaction: N₂(g) + 3 H₂(g) = 2 NH3(g)? (A) Kc = [N₂][H₂]³ (B) Kc (C) Kc (D) Kc = (E) Kc = = 3 = 2[NH3] [N₂] + 3[H₂] [N₂] + 3[H₂] 2[NH3] 2 [NH3]² [N₂][H₂]³ 3 [N₂] [H₂]³ [NH3]²(Q26 C-b). Find the oxidation number of the underlined element in the following: (1) CH,O6 ? (ii) Mo2O5Amylene C5H10 and acetic acid react to give the ester according to the reaction; C5H10 + CH3COOH=CH3COOC5H11What is the value of Kc if 0.00645 mole of amylene and 0.001 mole of acetic acid mixed in 845 ml of a certain inert solvent react to give 0.000784 mole of ester?
- 1. During the degradation of ethyl acetate (C4H3O2) with dichromate reactions occur as given below; balance the reactions: Total reaction: C4H3O2 + Cr20,2-+ H* Cr3* + CO2 + H2OBalance the following redox reactions, to their simplest form, by supplying the correct coefficients before each compound for #s 1-15. The unknown coefficients of the compounds should be whole numbers. Note: The reactions below are not yet balanced.(d) When butane, CHSCH:CH:CHsand bromine gas, Brz is exposed to sunlight, monobrominated product are produced. The reaction equation is glven below: Apabila butana, CH:CH2CH2CH3 dan gas bromin, Brz terdedah kepada cahaya matahari, produk pembrominan tunggal dihasilkan. Persamaan tindak balas diberikan di bawah: UV CH;CH,CH,CH, - Bry B.
- (c) (d) Н (e) НО HO ОН н Na₂Cr₂O7 H2SO4, H2O 1. LiAIH4 2. H2O workup 3. PCC 4. (Ph)3PCH2 OH H2SO4 (catalytic)Chemistry The compound YBa2Cu3O7 is known as a defect perovskite. What does this mean if you were to describe the structure of “YBCO”? Based on what you have learned from the solid-state modeling kits, what can be said about the building blocks of compounds like these?= (b) Calculate the pH of 0.0005 mol dm³ ethanoic acid when its pK₁ = 4.75 à CH₂COOH(aq) CH₂COO (aq) + Ht (aq) = K₁ pH =